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Merck
CN

740497

2-[[(十二烷基巯基)硫代甲基]硫代]-2-甲基苯甲酸甲酯

97% (HPLC)

别名:

2 - [[(十二烷基巯基)硫代甲基]硫代] - 2 - 甲基苯甲酸甲酯

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关于此项目

经验公式(希尔记法):
C18H34O2S3
化学文摘社编号:
分子量:
378.66
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Quality Level

assay

97% (HPLC)

form

liquid

refractive index

n20/D 1.517

density

1.008 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OC

InChI

1S/C18H34O2S3/c1-5-6-7-8-9-10-11-12-13-14-15-22-17(21)23-18(2,3)16(19)20-4/h5-15H2,1-4H3

InChI key

NHWLEOYMZVCNBC-UHFFFAOYSA-N

General description

需要帮助选择正确的可逆加成-断裂链转移剂? 请翻阅单体目录里面的RAFT部分兼容性表格.

Application

用于可控自由基聚合的可逆加成 - 断裂链转移剂;特别适合苯乙烯,丙烯酸酯和丙烯酰胺单体聚合。链转移剂(CTA)


pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

140.0 °F

flash_point_c

60 °C

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

商品

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.


RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being



全球贸易项目编号

货号GTIN
740497-5G04061832978338
740497-1G04061826280775