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Merck
CN

740497

Sigma-Aldrich

2-[[(十二烷基巯基)硫代甲基]硫代]-2-甲基苯甲酸甲酯

97% (HPLC)

别名:

2 - [[(十二烷基巯基)硫代甲基]硫代] - 2 - 甲基苯甲酸甲酯

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About This Item

经验公式(希尔记法):
C18H34O2S3
分子量:
378.66
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

97% (HPLC)

形式

liquid

折射率

n20/D 1.517

密度

1.008 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OC

InChI

1S/C18H34O2S3/c1-5-6-7-8-9-10-11-12-13-14-15-22-17(21)23-18(2,3)16(19)20-4/h5-15H2,1-4H3

InChI key

NHWLEOYMZVCNBC-UHFFFAOYSA-N

一般描述

需要帮助选择正确的可逆加成-断裂链转移剂? 请翻阅单体目录里面的RAFT部分兼容性表格.

应用

用于可控自由基聚合的可逆加成 - 断裂链转移剂;特别适合苯乙烯,丙烯酸酯和丙烯酰胺单体聚合。链转移剂(CTA)

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

140.0 °F

闪点(°C)

60 °C

法规信息

危险化学品

分析证书(COA)

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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