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Merck
CN

740411

Sigma-Aldrich

叠氮化钾

≥99.9% trace metals basis

别名:

叠氮化钾

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About This Item

经验公式(希尔记法):
KN3
CAS号:
分子量:
81.12
EC 号:
MDL编号:
UNSPSC代码:
12352125
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

≥99.9% trace metals basis

表单

solid

mp

~300 °C (decomposition)

官能团

azide

SMILES字符串

[K+].[N-]=[N+]=[N-]

InChI

1S/K.N3/c;1-3-2/q+1;-1

InChI key

TZLVRPLSVNESQC-UHFFFAOYSA-N

应用

叠氮化钾可用作合成以下物质的试剂:
    在咪唑催化剂的存在下,3-O-(3-甲基磺酰氧基丙氧基)雌酮通过亲核叠氮作用得到
  • 3-O-(-3-叠氮丙基)雌酮
  • 在四丁基溴化铵作为催化剂的存在下,由 α-溴代苯乙酮衍生物得到叠氮苯甲酰基衍生物
  • 在三氟甲磺酸铜作为催化剂的存在下由(4-氟苯基)三氟硼酸钾制备得到 1-叠氮-4-氟苯

象形图

Skull and crossbones

警示用语:

Danger

危险声明

预防措施声明

危险分类

Acute Tox. 2 Oral

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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A M Liashchuk et al.
Zhurnal mikrobiologii, epidemiologii, i immunobiologii, (4)(4), 65-68 (2006-09-01)
A highly purified TUL4-CBD chimeric protein was obtained by one stage purification method. TUL4-CBD protein consists of TUL4 Francisella tularensis mature peptide sequence, Gly-Ser spacer and cellulose binding domain (CBD) of Anaerocellum thermophilum. The TUL4-CBD protein was shown to induce
tert-Alcohol-functionalized imidazolium ionic liquid: catalyst for mild nucleophilic substitution reactions at room temperature
Shinde S, et al.
Tetrahedron Letters, 50, 6654-6657 (2009)
An efficient method for synthesis of phenacyl derivatives under homogeneous phase transfer catalyst condition in aqueous media
Sayyahi S, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22, 300-302 (2011)
A M Egorov et al.
Biochimica et biophysica acta, 659(1), 141-149 (1981-05-14)
Modification of 12 arginine residues per molecule of formate dehydrogenase (formate : NAD+ oxidoreductase, EC 1.2.1.2.) from the methylotrophic bacterium, Achromobacter parvulus I, by 2,3-butanedione results in complete inactivation of the enzyme. Inactivation of the enzyme is reversible and proceeds
Copper-mediated functionalization of aryl trifluoroborates
Schimler S, et al.
Synlett, 27, 2279-2284 (2016)

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