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Merck
CN

736325

Sigma-Aldrich

聚(乙二醇)甲醚2-(十二烷基硫基硫代羰基硫基)-2-甲基丙酸酯

average Mn 6,000

别名:

PEG DDMAT macroCTA, 甲氧基聚(环氧乙烷)-2-(十二烷基硫基硫代羰基硫基)-2-甲基丙酸酯

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About This Item

UNSPSC代码:
12162002
NACRES:
NA.23

形式

solid

分子量

average Mn 6,000

mp

268-271 °C
51-56 °C

PDI

≤1.1

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应用

用于受控自由基聚合的RAFT试剂;特别适用于苯乙烯、丙烯酸酯和丙烯酰胺单体的聚合,以制备在光刻和生物学上具有重要功能的PEG嵌段共聚物。链转移剂(CTA)

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)

商品

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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