所有图片(1)
About This Item
经验公式（希尔记法）:
C4H7BrO2Zn
分子量:
232.39
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
形式
liquid
质量水平
反应适用性
reaction type: C-C Bond Formation
浓度
0.6 M in THF
密度
0.992 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
Br[Zn]CC1OCCO1
InChI
1S/C4H7O2.BrH.Zn/c1-4-5-2-3-6-4;;/h4H,1-3H2;1H;/q;;+1/p-1
InChI key
LOJRLQRGBKTHDB-UHFFFAOYSA-M
一般描述
(1,3-Dioxolan-2-ylmethyl)zinc bromide is an organozinc compound used as a reagent in Negishi cross-coupling reaction to prepare aryl or heteroaryl scaffolds via C-C bond formation.
应用
(1,3-Dioxolan-2-ylmethyl)zinc bromide can be used as a reagent in the allylic alkylation reactions in the presence of iridium catalyst.
法律信息
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
-22.0 °F
闪点(°C)
-30 °C
法规信息
危险化学品
Iridium-Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides
Hamilton JY, et al.
Angewandte Chemie (International ed. in English), 54(26), 7644-7647 (2015)
Synthesis of 8-C-substituted 2, 6-diaminopurine acyclic nucleoside phosphonates by Negishi cross-coupling
Sedlavcek O, et al.
Collection of Czechoslovak Chemical Communications, 10(26), 449-450 (2015)
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