所有图片(1)
About This Item
经验公式（希尔记法）:
C34H52Cl2FeP2Pd
CAS号:
分子量:
755.90
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
98%
表单
powder
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
294-300 °C
储存温度
−20°C
SMILES字符串
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
InChI
1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
InChI key
HRAMBTUEZQOQRK-UHFFFAOYSA-L
相关类别
应用
1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of:
- α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
- Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids.
- α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Palladium-catalyzed hydroaminocarbonylation of alkynes with tertiary amines via C-N bond cleavage
Gao, Bao and Huang, Hanmin
Organic Letters, 19(22), 6260-6263 (2017)
Suzuki-Miyaura coupling of quinazolines containing an unprotected NH2 group: Synthesis and biological testing of quinazoline derivatives
Pulipati Y, et al.
Synthetic Communications, 47(12), 1142-1150 (2017)
A highly practical and general route for α-arylations of ketones using Bis-phosphinoferrocene-based palladium catalysts
Grasa GA and Colacot TJ
Organic Process Research & Development, 12(3), 522-529 (2008)
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