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Merck
CN

697400

Sigma-Aldrich

3-己基噻吩-2-硼酸频哪醇酯

95%

别名:

2-(3-己基-2-噻吩基)-4,4,5,5-四甲基-1,3,2-二氧杂硼烷

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About This Item

经验公式(希尔记法):
C16H27BO2S
分子量:
294.26
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

95%

表单

liquid

折射率

n20/D 1.490-1.499

密度

0.983 g/mL at 25 °C

SMILES字符串

CCCCCCc1ccsc1B2OC(C)(C)C(C)(C)O2

InChI

1S/C16H27BO2S/c1-6-7-8-9-10-13-11-12-20-14(13)17-18-15(2,3)16(4,5)19-17/h11-12H,6-10H2,1-5H3

InChI key

XCXAUPBHQCCWCI-UHFFFAOYSA-N

应用

Reagent used for
  • Suzuki-Miyaura cross-coupling reactions
  • p-type/n-type switching of ambipolar bithiazole-benzothiadiazole-based polymers in solar cells
  • Hierarchical self-assembly of semiconductor functionalized peptide a-helixes and optoelectronic properties

Reagent used in Preparation of
  • Photovoltaic materials, polymers, and thiophene-based compounds with photophysical, electrochemical, and fluorescent properties
  • Polymer solar cells for Low band gap poly(1,4-arylene-2,5-thienylene)s with benzothiadiazole units
  • Dithienothiophene-based dyes for dye-sensitized solar cells

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

>230.0 °F

闪点(°C)

> 110 °C

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Photovoltaic response to structural modifications on a series of conjugated polymers based on 2-aryl-2H-benzotriazoles
Pasker, F. M.; et al.
Journal of Polymer Science Part A: Polymer Chemistry, 49, 5001-5011 (2011)
Tae-Hyuk Kwon et al.
The Journal of organic chemistry, 76(10), 4088-4093 (2011-04-14)
A one-pot synthesis of 2,6-dibromodithieno[3,2-b;2',3'-d]thiophene (dibromo-DTT, 4) was developed. A key step was bromodecarboxylation of DTT-2,6-dicarboxylic acid, obtained by saponification of the diester 1. The donor-acceptor dye DAHTDTT (13), based on a central 2,6-bis[2'-(3'-hexylthienyl)]dithieno[3,2-b;2',3'-d]thiophene core (9), was prepared and incorporated
Low band gap poly(1,4-arylene-2,5-thienylene)s with benzothiadiazole units: Synthesis, characterization and application in polymer solar cells
Operamolla, A.; et al.
Solar Energy Mat. and Solar Cells, 95, 3490-3503 (2011)
Photophysical and Electrochemical Properties of Thiophene-Based 2-Arylpyridines
Coluccini, C.; et al.
European Journal of Organic Chemistry, 28, 5587-5598 (2011)
p/n Switching of Ambipolar Bithiazole-Benzothiadiazole-Based Polymers in Photovoltaic Cells
Balan, B.; et al.
Macromolecules, 45, 2709-2719 (2012)

商品

Oligothiophenes are important organic electronic materials which can be produced using synthetic intermediates and Suzuki coupling.

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