所有图片(1)
别名:
2-二苯基膦-2′-(N,N-二甲基氨基)联苯, 2′-(二苯基膦基)-N,N′-二甲基--(1,1′-联苯)-2-胺, PhDavePhos
经验公式（希尔记法）:
C26H24NP
推荐产品
质量水平
检测方案
97%
形式
powder
反应适用性
reaction type: Cross Couplings
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: C-C Bond Formation
mp
122-126 °C
官能团
phosphine
SMILES字符串
CN(C)c1ccccc1-c2ccccc2P(c3ccccc3)c4ccccc4
InChI
1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3
InChI key
JGFXUYLYPITYGR-UHFFFAOYSA-N
应用
法律信息
用法以美国专利 6307087 和 6395916 为准。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
商品
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
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