695874
2-二叔丁基膦-2′-(N,N-二甲氨基)联苯
solid
别名:
tBuDavePhos
选择尺寸
关于此项目
产品名称
2-二叔丁基膦-2′-(N,N-二甲氨基)联苯,
SMILES string
CN(C)c1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C
InChI
1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3
InChI key
PHLPNEHPCYZBNZ-UHFFFAOYSA-N
form
solid
reaction suitability
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: C-X Bond Formation
mp
114-118 °C
functional group
phosphine
Quality Level
Application
Dialkylbiaryl phosphine ligand often used for Pd-catalyzed reactions in a range of contexts.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
相关内容
The Buchwald group has developed a series of highly active and versatile palladium precatalysts and biarylphosphine ligands used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The ligands are electron-rich, and highly tunable to provide catalyst systems with a diverse scope, high stability and reactivity. Furthermore, the new series of precatalysts are air-, moisture and thermally-stable and display good solubility in common organic solvents. The use of precatalysts ensures the efficient generation of the active catalytic species and allows one to accurately adjust the ligand:palladium ratio. The ligands, precatalysts and methodology developed in the Buchwald group are user friendly and have rendered previously difficult cross couplings reactions, much easier to achieve.
Buchwald Portfolio: Palladacycles and Ligands
Phosphine Ligand Application Guide
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