所有图片(1)
About This Item
经验公式（希尔记法）:
C26H44FeP2
CAS号:
分子量:
474.42
MDL编号:
UNSPSC代码:
12350000
PubChem化学物质编号:
NACRES:
NA.22
形式
solid
质量水平
反应适用性
reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Indole Forming Reactions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
mp
73-75 °C
官能团
phosphine
SMILES字符串
[Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C
InChI
1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;
InChI key
FPLSJBJGQLJLSV-UHFFFAOYSA-N
应用
形成二烯络合物；羰基插入；环加成；还原和脱氧。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Darbasie, N. D.; Schnatter, W. F. K. et al.
Tetrahedron Letters, 47, 963-963 (2004)
Sergeyev, S.; Hesse, M.
Synlett, 8, 1313-1313 (2002)
Sean H Wiedemann et al.
The Journal of organic chemistry, 71(5), 1969-1976 (2006-02-25)
The inter- and intramolecular couplings of unactivated alkenes to 3,4-dihydroquinazolines with a Rh(I) catalyst are reported. Coupling between olefins and NH-3,4-dihydroquinazoline was found to occur consecutively with heterocycle dehydrogenation in the presence of a Rh(I)/PCy3/HCl catalyst. The reaction was used
Anthony J Pearson et al.
Journal of the American Chemical Society, 125(44), 13326-13327 (2003-10-30)
A convenient one-pot procedure to prepare angularly substituted bicyclic and tricyclic molecules with excellent diastereoselectivity in good yield was developed, by Fe(CO)5 promoted cyclization. Three transformations (complexation, isomerization, and cyclization) were realized in a single operation. The product of this
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