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Merck
CN

692352

Sigma-Aldrich

双(六甲基二硅叠氮)镁

97%

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别名:
Mg(HMDS)2, 双(六甲基二硅杂叠氮基)镁
经验公式(希尔记法):
C12H36MgN2Si4
分子量:
345.07
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

solid

mp

121-124 °C

SMILES字符串

C[Si](C)(C)N([Mg]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/2C6H18NSi2.Mg/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2

InChI key

WYPTZCBYSQFOQS-UHFFFAOYSA-N

应用

双(六甲基二硅氮化物)镁是合成 rac -丙交酯大范围配基配合物的重要前体。 也可用于合成 ItBu:Mg[N(SiMe3)2]2,其中 I t Bu =(1,3-二--丁基咪唑-2-亚基),该催化剂用于碳化二亚胺加胺的鸟苷酸化反应。

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

补充剂危害

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Stereoselectivity switch between zinc and magnesium initiators in the polymerization of rac-lactide: different coordination chemistry, different stereocontrol mechanisms.
Wang H, et al.
Macromolecules, 47(22), 7750-7764 (2014)
Highly active magnesium initiators for ring-opening polymerization of rac-lactide.
Wang L and Ma H
Macromolecules, 43(16), 6535-6537 (2010)
Catalytic C?N bond formation in guanylation reaction by N-heterocyclic carbene supported magnesium (II) and zinc (II) amide complexes.
Baishya A, et al.
Journal of Organometallic Chemistry, 769, 112-118 (2014)
Dong Chen et al.
Nanoscale, 11(48), 23173-23181 (2019-11-30)
CoSe2 materials with different nanostructures are used as pseudocapacitive Mg-storage cathodes, which exhibit fast solid-state Mg2+ ions diffusion kinetics. In this work, CoSe2 with different nanostructures including hollow microspheres (H-CoSe2), nano-polyhedra (P-CoSe2) and nanorods (R-CoSe2) are fabricated by using facile
Yan Xu et al.
Nano letters, 19(5), 2928-2934 (2019-04-02)
The Mg/S battery is attractive because of its high theoretical energy density and the abundance of Mg and S on the earth. However, its development is hindered by the lack of understanding to the underlying electrochemical reaction mechanism of its

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