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Merck
CN

689785

Sigma-Aldrich

(S)-3,3′-双(2,4,6-三异丙基苯基)-1,1′-联萘-2,2′-双磷酸氢酯

greener alternative

≥97.0% (qNMR)

别名:

(11bS)-4-羟基-2,6-双[2,4,6-三(1-甲基乙基)苯基]二萘并[2,1-d:1′,2′-f]-1,3,2-二氧杂膦 4-氧化物, (S)-3,3′-双(2,4,6-三异丙基苯基)-1,1′-二-2-萘酚环一磷酸酯, (S)-TRIP

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About This Item

经验公式(希尔记法):
C50H57O4P
分子量:
752.96
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

≥97.0% (qNMR)

表单

lumps

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

官能团

phosphate

环保替代产品分类

SMILES字符串

CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2cc3ccccc3c-4c2OP(O)(=O)Oc5c(cc6ccccc6c-45)-c7c(cc(cc7C(C)C)C(C)C)C(C)C

InChI

1S/C50H57O4P/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47-48-38-20-16-14-18-34(38)22-44(50(48)54-55(51,52)53-49(43)47)46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12/h13-32H,1-12H3,(H,51,52)

InChI key

AGQAQYPGJDBIQR-UHFFFAOYSA-N

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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