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Merck
CN
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文件

681482

Sigma-Aldrich

2-(烯丙基二甲基甲硅烷基)吡啶

90%

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别名:
烯丙基二甲基(2-吡啶基)硅烷
线性分子式:
(CH2CHCH2)Si(CH3)2(C5H4N)
CAS号:
118722-54-6
分子量:
177.32
MDL编号:
MFCD09265157
UNSPSC代码:
12352103
PubChem化学物质编号:
24885637
NACRES:
NA.22

检测方案

90%

折射率

n20/D 1.5046

密度

0.913 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

C[Si](C)(CC=C)c1ccccn1

InChI

1S/C10H15NSi/c1-4-9-12(2,3)10-7-5-6-8-11-10/h4-8H,1,9H2,2-3H3

InChI key

WIRIPVDRZYVTCG-UHFFFAOYSA-N

相关类别

应用

2-(Allyldimethylsilyl)pyridine can be used as a pyridyl transfer reagent to prepare substituted pyridine derivatives by reacting with various aryl iodides in the presence of a palladium catalyst and silver(I) oxide activator. It can also be utilized as a coupling reagent in the allylation of carbonyl compounds using a copper catalyst.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

预防措施声明

P261 - P305 + P351 + P338

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Toshiki Nokami et al.
Organic letters, 8(4), 729-731 (2006-02-14)
[reaction: see text] (2-Pyridyl)allyldimethylsilanes were found to be novel pyridyl transfer reagents in palladium-catalyzed cross-coupling reactions of various aryl iodides in the presence of silver(I) oxide as an activator.
Copper-catalyzed allylation of carbonyl derivatives using allyl (2-pyridyl) silanes
Kamei T, et al.
Organic Letters, 7(21), 4725-4728 (2005)
Palladium-catalyzed cross-coupling reactions of (2-pyridyl) allyldimethylsilanes with aryl iodides
Nokami T, et al.
Organic Letters, 8(4), 729-731 (2006)

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