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表单
solid
质量水平
SMILES字符串
OP1(=O)Oc2c(c(cc3ccc4ccccc4c23)-c5ccccc5)-c6c(O1)c7c(ccc8ccccc78)cc6-c9ccccc9
InChI
1S/C40H25O4P/c41-45(42)43-39-35-29(21-19-27-15-7-9-17-31(27)35)23-33(25-11-3-1-4-12-25)37(39)38-34(26-13-5-2-6-14-26)24-30-22-20-28-16-8-10-18-32(28)36(30)40(38)44-45/h1-24H,(H,41,42)
InChI key
YKIJNEDTUDPMNC-UHFFFAOYSA-N
相关类别
应用
磺胺加成到 Boc-活化芳基亚胺反应中的手性布朗斯特酸催化剂。
Catalyst involved in:
- Desymmetrization of meso-aziridines
- Asymmetric aza-Darzens aziridine synthesis
- Enantioselective ring-opening of mono-and bicyclic N-acyl meso aziridines
- Condensation of aldehydes with amino benzenesulfonamides
- Pictet-Spengler reactions
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Journal of the American Chemical Society, 127(45), 15696-15697 (2005-11-10)
A new method for the Brønsted acid-catalyzed addition of amide nucleophiles to imines to produce protected aminal products is described. Simple Brønsted acids (phenyl phosphinic acid and trifluoromethanesulfonimide) were shown to be excellent catalysts, providing high yields of the aminal
商品
TRIP和TiPSY手性磷酸催化剂
TRIP and TiPSY Chiral Phosphoric Acid Catalysts
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