673307
三(乙腈基)环戊二烯六氟磷酸钌
solid
别名:
(环戊二烯基三(乙腈)六氟磷酸钌, 三(乙腈基)环戊二烯基钌六氟磷酸
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选择尺寸
关于此项目
线性分子式:
[(C5H5)Ru(CH3CN)3]PF6
化学文摘社编号:
分子量:
434.28
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
三(乙腈基)环戊二烯六氟磷酸钌,
SMILES string
[Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
InChI
1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1
InChI key
HJQVFVSAQOQXRG-UHFFFAOYSA-N
form
solid
reaction suitability
core: ruthenium
reagent type: catalyst
storage temp.
2-8°C
Quality Level
Application
用于催化：
- 亲核试剂的区域选择性和立体选择性脱水烯丙基化
- O-H插入和缩合反应
- 硅氢加成
- 脱羧烯丙基醚化
- 未活化烯丙基乙烯醚的克莱森重排
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Xiuzhong Zhu et al.
Polymers, 11(4) (2019-04-10)
A series of side-chain functionalized polytetrahydrofuran (PTHF) derivatives were synthesized via the blue-light photocatalytic thiol-ene "click" reaction. Firstly, unsaturated polytetrahydrofuran (UPTHF) as a new unsaturated polyether was synthesized via condensation polymerization of cis-2-butene-1,4-diol and trans-1,4-dibromo-2-butene using potassium hydroxide (KOH) as
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