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Merck
CN

671444

Sigma-Aldrich

1,3-二甲基咪唑二甲基膦

≥98.0% (HPLC)

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别名:
[MMIM][DMP]
经验公式(希尔记法):
C7H15N2O4P
分子量:
222.18
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

≥98.0% (HPLC)

杂质

≤1.0% water

SMILES字符串

COP([O-])(=O)OC.Cn1cc[n+](C)c1

InChI

1S/C5H9N2.C2H7O4P/c1-6-3-4-7(2)5-6;1-5-7(3,4)6-2/h3-5H,1-2H3;1-2H3,(H,3,4)/q+1;/p-1

InChI key

GSGLHYXFTXGIAQ-UHFFFAOYSA-M

相关类别

一般描述

1,3-Dimethylimidazolium dimethyl phosphate is an imidazolium-based phosphoric ionic liquid that can be prepared by reacting 1-methylimidazole with trimethyl phosphate. The pretreatment of sugarcane bagasse with [MMIM][DMP] yields glucose and xylose via enzymatic saccharification.

应用

1,3-Dimethylimidazolium dimethyl phosphate ([MMIM][DMP]) can be used as a catalyst and a solvent for the preparation of ethyl 2-cyano-3-phenylpropenoate from benzaldehyde and ethyl cyanoacetate via Knoevenagel condensation. It can also be used to produce bioethanol from sugarcane bagasse by enzymatic hydrolysis.

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Extractive desulfurization of gasoline using imidazolium-based phosphoric ionic liquids.
Nie Y, et al.
Energy and Fuels, 20(5), 2083-2087 (2006)
Imidazolium dialkylphosphates-a class of versatile, halogen-free and hydrolytically stable ionic liquids.
Kuhlmann E, et al.
Green Chemistry, 9(3), 233-242 (2007)
Dialkylimidazolium dimethyl phosphates as solvents and catalysts for the Knoevenagel condensation reaction.
Zicmanis A and Anteina L.
Tetrahedron Letters, 55(12), 2027-2028 (2014)
Samaneh Bahrani et al.
Bioresource technology, 185, 411-415 (2015-03-26)
In this study, an imidazolium-based ionic liquid (IL), 1,3-dimethylimidazolium dimethyl phosphate ([Mmim][DMP]), was applied for pretreating sugarcane bagasse to produce bioethanol. The main goal of this study was to investigate the feasibility of bagasse pretreatment with this IL, and to
Major improvement in the rate and yield of enzymatic saccharification of sugarcane bagasse via pretreatment with the ionic liquid 1-ethyl-3-methylimidazolium acetate ([Emim][Ac]).
da Silva ASA, et al.
Bioresource Technology, 102(22), 10505-10509 (2011)

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