667412
五甲基环戊二烯基三（乙腈）钌 (II) 六氟磷酸盐
solid
别名:
[RuCp*(MeCN)3]PF6
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关于此项目
经验公式（希尔记法）:
C16H24N3PRuF6
化学文摘社编号:
分子量:
504.42
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
五甲基环戊二烯基三（乙腈）钌 (II) 六氟磷酸盐,
SMILES string
[Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C
InChI key
IYEMDYLFXFMECZ-UHFFFAOYSA-N
InChI
1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;3*1H3;;/q;;;;-1;+1
form
solid
reaction suitability
core: ruthenium
reagent type: catalyst
storage temp.
2-8°C
Quality Level
General description
五甲基环戊二烯基三(乙腈)六氟磷酸钌(II)是一种有机钌化合物。它在有机合成中用作均相催化剂。它能够实现炔烃氢化硅烷化、炔烃环三聚化、环加成和碳-碳或碳-杂原子成键反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes.
B M Trost et al.
Journal of the American Chemical Society, 123(50), 12726-12727 (2001-12-14)
Barry M Trost et al.
Journal of the American Chemical Society, 127(50), 17644-17655 (2005-12-15)
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to alpha-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans addition process is at work. The same complex
商品
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
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