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Merck
CN

663212

Sigma-Aldrich

异丙烯基硼酸频哪醇酯

contains phenothiazine as stabilizer, 95%

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别名:
2-异丙烯基-4,4,5,5-四甲基-1,3,2-二氧杂硼烷
经验公式(希尔记法):
C9H17BO2
分子量:
168.04
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

95%

包含

phenothiazine as stabilizer

折射率

n20/D 1.4320

bp

47-49 °C/9 mbar

密度

0.894 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

CC(=C)B1OC(C)(C)C(C)(C)O1

InChI

1S/C9H17BO2/c1-7(2)10-11-8(3,4)9(5,6)12-10/h1H2,2-6H3

InChI key

SVSUYEJKNSMKKW-UHFFFAOYSA-N

应用

Reagent used for
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling processes
  • Inverse-electron-demand Diels-Alder reaction
  • Simmons-Smith Cyclopropanation Reaction
  • Polyene cyclization
  • Stereoselective aldol reactions
  • Grubbs cross-metathesis reaction
  • Intramolecular Suzuki-Miyaura reaction
  • Stereoselective cross-metathesis
  • Dipolar cycloaddition
  • Iodosulfonylation
  • Asymmetric conjugate addition and intramolecular hydroacylation

Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors
Reagent used for
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions
  • Inverse-electron-demand Diels-Alder reaction
  • Simmons-Smith Cyclopropanation Reaction
  • Polyene cyclization
  • Stereoselective aldol reactions
  • Grubbs cross-metathesis reaction
  • Intramolecular Suzuki-Miyaura reaction
  • Stereoselective cross-metathesis
  • Dipolar cycloaddition
  • Iodosulfonylation
  • Asymmetric conjugate addition and intramolecular hydroacylation

Reagent used in preparation of various therapeutic kinase and enzymatic inhibitors

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

107.6 °F

闪点(°C)

42 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Evaluation of thieno[3,2-b]pyrrole[3,2-d]pyridazinones as activators of the tumor cell specific M2 isoform of pyruvate kinase
Jiang, J-k.; et al.
Bioorganic & Medicinal Chemistry, 20, 3387-3393 (2010)
Total synthesis of apoptolidinone.
Bin Wu et al.
Angewandte Chemie (International ed. in English), 43(48), 6673-6675 (2004-12-14)
Catalytic asymmetric intramolecular hydroacylation with rhodium/phosphoramidite-alkene ligand complexes.
Thomas J Hoffman et al.
Angewandte Chemie (International ed. in English), 50(45), 10670-10674 (2011-09-20)
Simmons-Smith cyclopropanation reaction
Charette, A. B.; Beauchemin, A.
Org. React., 58 (2001)
Yu-Jun Zhao et al.
Organic letters, 10(11), 2143-2145 (2008-04-29)
The first asymmetric total synthesis of antiochic acid using bioinspired polyene cyclization strategy is described. Both good yield and good asymmetric induction were obtained.

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