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文件

663131

2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯

Name: 2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯
Brand: ALDRICH

98%

别名:

RuPhos

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所有图片(5)

About This Item

经验公式（希尔记法）:

C₃₀H₄₃O₂P

CAS号:

787618-22-8

分子量:

466.64

MDL编号:

MFCD06798294

UNSPSC代码:

12352112

PubChem化学物质编号:

24884189

NACRES:

NA.22

质量水平

300

检测方案

98%

形式

solid

反应适用性

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

环保替代产品得分

old score: 3
new score: 1
Find out more about DOZN™ Scoring

环保替代产品特性

Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

1-5% Bis(2′,6′-Diisopropoxybiphenyl)cyclohexylphosphine

mp

123-126 °C

官能团

phosphine

环保替代产品分类

Re-engineered,

SMILES字符串

CC(C)Oc1cccc(OC(C)C)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4

InChI

1S/C30H43O2P/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25/h11-13,18-25H,5-10,14-17H2,1-4H3

InChI key

MXFYYFVVIIWKFE-UHFFFAOYSA-N

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一般描述

我们竭诚为您带来满足绿色替代产品四大类别要求的替代产品。本品属于重新设计产品类别，在“原子经济”、“设计要有能效”和“使用可再生的原料”绿色化学原则方面取得了重大进步。点击此处查看其DOZN记分卡。

应用

大体积膦配体，用于氨基乙基三氟硼酸盐和缺电子芳基溴化物的钯催化交叉偶联反应。

对于小规模和高通量应用，可选用ChemBeads形式(932205)

法律信息

专利使用：EP 1097158；JP 5758844；CA 2336691

918008

GPhos, ≥95%

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

分析证书(COA)

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Beta-aminoethyltrifluoroborates: efficient aminoethylations via Suzuki-Miyaura cross-coupling.

Gary A Molander et al.

Organic letters, 9(2), 203-206 (2007-01-16)

A set of phenethylamines has been successfully prepared via Suzuki-Miyaura cross-coupling of diverse potassium beta-aminoethyltrifluoroborates with aryl halides. The potassium beta-aminoethyltrifluoroborates were easily prepared via hydroboration of enamine and enamide precursors. [reaction: see text].

Biaryl phosphane ligands in palladium-catalyzed amination.

David S Surry et al.

Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

David S Surry et al.

Chemical science, 2(1), 27-50 (2011-01-01)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Ruben Martin et al.

Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon

商品

Buchwald Phosphine Ligands

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