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表单
nanoparticles
wet
质量水平
包含
0.35-0.43 mmol/g pallladium(0) (dry basis)
45% water
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
标记范围
0.4 mmol/g Pd(0) loading (dry basis)
重量
Unit weight includes weight of water.
一般描述
Pd(0) EnCat® 30NP may be used as a catalyst for the selective reduction of aromatic aldehydes, ketones and epoxides to form the corresponding alcohols via hydrogenation.
其他说明
囊化的钯催化剂，可催化芳基酮和苄醚类化合物的还原。
基质含量 30%
法律信息
Pd EnCat 技术已申请国际专利，包括 PCT/GB 02/03135
EnCat is a registered trademark of Reaxa Ltd.
警示用语：
Danger
危险声明
危险分类
Self-heat. 1
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Steven V Ley et al.
Organic letters, 5(24), 4665-4668 (2003-11-25)
[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.
相关内容
Homogeneous palladium catalysts are widely utilized due to their versatility, reactivity and functional group tolerance.
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