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Merck
CN

642452

五氯化钼

powder, 99.99% trace metals basis (excluding W)

别名:

Molybdenum pentachloride, Molybdenum(5+) chloride

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关于此项目

线性分子式:
MoCl5
化学文摘社编号:
分子量:
273.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-575-3
MDL number:
Assay:
99.99% trace metals basis (excluding W)
Grade:
anhydrous
Form:
powder
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产品名称

五氯化钼, powder, 99.99% trace metals basis (excluding W)

InChI key

GICWIDZXWJGTCI-UHFFFAOYSA-I

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

SMILES string

Cl[Mo](Cl)(Cl)(Cl)Cl

grade

anhydrous

vapor pressure

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

assay

99.99% trace metals basis (excluding W)

form

powder

reaction suitability

core: molybdenum

impurities

≤150.0 ppm Trace Metal Analysis

bp

268 °C (lit.)

mp

194 °C (lit.)

density

2.928 g/mL at 25 °C (lit.)

application(s)

electroplating
material synthesis precursor

Quality Level

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Application

氯化钼(V) 可用于:
  • 作为催化剂用于仲苄醇 的酰胺化。
  • 作为前体用于通过原子层沉积法制备MoS2薄膜 。
  • 作为丁二烯配位聚合的 主要催化剂。
  • 制备用于钠离子和 锂离子电池的优良负极材料。
  • 作为Li–O2电池的双功能氧化还原介体,用于克服高极化和低能量密度问题。

General description

氯化钼(V) ,也称五氯化钼,是一种路易斯酸,具有高氧化电位。它被广泛用作有机合成和聚合物化学领域的催化剂。它也用作化学气相沉积的前体。

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Atomic layer deposition of a MoS2 film
Lee Kheng Tan, et al.},
Nanoscale, 6, 10584-10588 (2014)
m-Cresol-substituted triethyl aluminum/MoCl5/TBP catalytic system for coordination polymerization of butadiene
Peipei Li, et al.
Iranian Polymer Journal, 27, 537-544 (2018)
Molybdenum(V) chloride-catalyzed amidation of secondary benzyl alcohols with sulfonamides and carbamates
Ch. Raji Reddy, et al.},
Tetrahedron Letters, 48, 7169-7172 (2007)
Towards high-volumetric performance of Na/Li-ion batteries: A better anode material with molybdenum pentachloride--graphite intercalation compounds (MoCl 5--GICs
Zheng Li, et al.
Journal of Materials Chemistry, 8, 2430-2438 (2020)
MoCl5 as a dual-function redox mediator for Li-O2 batteries
Xin-Gai Wang, et al.
Journal of Materials Chemistry, 7, 14239-14243 (2019)

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