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Merck
CN
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文件

639230

Sigma-Aldrich

碳纳米管，单壁，聚苯胺磺酸官能化

75-85% carbon basis, D × L 1.1 nm × 0.5-1.0 μm , bundle dimensions, avg. no. of layers, 1

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别名:
SWNT，PABS 官能化, 碳纳米管，单壁，PABS 官能化
MDL编号:
MFCD05865412
UNSPSC代码:
12352103
NACRES:
NA.23

质量水平

100

检测方案

75-85% carbon basis

形式

powder

分子量

average Mw 400-600 g/mol (PABS)

特点

avg. no. of layers 1

标记范围

65% (PABS, typical)

直径 × 长度

1.1 nm × 0.5-1.0 μm , bundle dimensions

杂质

4% metals

溶解性

ethanol: 0.05 mg/mL
DMF: 0.1 mg/mL
H2O: 5.0 mg/mL (As determined by near-IR absorbance spectroscopy.)

官能团

sulfonic acid

相关类别

一般描述

各 SWCNT 的平均直径 = 1.4nm ± 0.1nm

应用

在水中分散的方法： 在固体形式下，SWNTs在宏观粒子中高度缠结。打破这种关联并使得材料溶于溶液，需要付出巨大的努力。将50 mg材料在2 ml水中超声处理30 min。添加8 ml水，再超声处理90 min。通常，在该程序完成后，根据目视观察，所有材料均完全分散。对于溶解度的定量测量，让分散液在室温下静置过夜。 由于浓缩分散液的高光密度，将所研究分散液上层的等分试样稀释100倍。 根据记录的NIR光谱，使用9750 cm-1处与标准溶液浓度相比的吸光度图，估计稀释溶液的浓度（见参考文献）。

包装

玻璃瓶封装

制备说明

电弧放电法

分析说明

含碳量

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H319,H335

危险分类

Eye Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Bin Zhao et al.
Journal of the American Chemical Society, 127(22), 8197-8203 (2005-06-02)
Poly(aminobenzene sulfonic acid) (PABS) and polyethylene glycol (PEG) were covalently attached to single-walled carbon nanotubes (SWNTs) to form water-soluble graft copolymers. Quantitative near-IR (NIR) spectroscopic studies of these SWNT graft copolymers indicate a water solubility of about 5 mg/mL, and
Zhao, B. et al
Advances in Functional Materials, 14, 71-71 (2004)
Nano Letters, 3, 309-309 (2003)

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