质量水平
检测方案
≥95%
形式
powder
mp
197-200 °C (lit.)
SMILES字符串
COC(=O)c1ccc(cc1)B(O)O
InChI
1S/C8H9BO4/c1-13-8(10)6-2-4-7(5-3-6)9(11)12/h2-5,11-12H,1H3
InChI key
PQCXFUXRTRESBD-UHFFFAOYSA-N
应用
作为试剂用于以下反应
- 串联型Pd(II)催化的氧化Heck反应和分子内C-H酰胺化序列
- 铜介导芳基硼酸与氟烷基碘的无连接有氧氟烷基化反应
- 芳基硼酸的一锅法积位硝化
- 铜催化硝化
- 环缩合和钯-膦催化的 Suzuki-Miyaura 偶联
- 试剂用于制备
- 镍催化的芳香卤化物与芳基硼酸的 Suzuki-Miyaura 交叉偶联反应研究 †
- 色烯酮及其缓激肽 B1 拮抗活性 †
- 铂纳米颗粒@光活性金属 - 有机骨架通过协同光激发和电子注入产生有效的氢析出 †
- 基于水杨酸盐的噻吩基苯甲酸作为大肠杆菌氨基肽氨肽酶抑制剂†
其他说明
含有不同量的酸酐
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Synthesis and biological evaluation of salicylate-based compounds as a novel class of methionine aminopeptidase inhibitors
Bioorganic & Medicinal Chemistry, 21, 7151-7154 (2011)
Journal of the American Chemical Society, 134(17), 7211-7214 (2012-04-11)
Pt nanoparticles of 2-3 nm and 5-6 nm in diameter were loaded into stable, porous, and phosphorescent metal-organic frameworks (MOFs 1 and 2) built from [Ir(ppy)(2)(bpy)](+)-derived dicarboxylate ligands (L(1) and L(2)) and Zr(6)(μ(3)-O)(4)(μ(3)-OH)(4)(carboxylate)(12) secondary building units, via MOF-mediated photoreduction of
Chromenones as potent bradykinin B1 antagonists
Bioorganic & Medicinal Chemistry, 22, 619-622 (2012)
A Highly Practical and Reliable Nickel Catalyst for Suzuki-Miyaura Coupling of Aryl Halides
Advanced Synthesis & Catalysis, 353, 2881-2881 (2011)
The Journal of organic chemistry, 77(4), 1798-1804 (2012-01-31)
A selective palladium-catalyzed Suzuki-Miyaura coupling reaction of polyfluorophenyl oxazolines through ortho C-F activation is described. It was found that reactions with DPPF as the ligand occurred much faster than those with other ligands. A variety of arylboronic acids including challenging
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