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577766

Sigma-Aldrich

六羰基钼

≥99.9% trace metals basis

别名:

羰化钼

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About This Item

线性分子式:
Mo(CO)6
CAS号:
13939-06-5
分子量:
264.00
EC 号:
237-713-3
MDL编号:
MFCD00003466
UNSPSC代码:
12352103
PubChem化学物质编号:
24880893
NACRES:
NA.23

蒸汽密度

9.1 (vs air)

质量水平

100

方案

≥99.9% trace metals basis

表单

solid
solid

纯化方式

sublimation

反应适用性

core: molybdenum
reagent type: catalyst

沸点

156 °C (lit.)

mp

150 °C (dec.) (lit.)

密度

1.96 g/mL at 25 °C (lit.)

SMILES字符串

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChI key

KMKBZNSIJQWHJA-UHFFFAOYSA-N

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相关类别

一般描述

基材原子序数：42 钼

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H331

危险分类

Acute Tox. 3 Inhalation

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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分析证书(COA)

Lot/Batch Number
0000326139
0000326138
0000314639
0000314639
0000326139

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Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
In situ generation of carbon monoxide from solid molybdenum hexacarbonyl. A convenient and fast route to palladium-catalyzed carbonylation reactions.
Nils-Fredrik K Kaiser et al.
Journal of combinatorial chemistry, 4(2), 109-111 (2002-03-12)
Patrik Nordeman et al.
The Journal of organic chemistry, 77(24), 11393-11398 (2012-12-05)
A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the
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