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About This Item
线性分子式:
InCl3 · aq
CAS号:
分子量:
221.18 (anhydrous basis)
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
反应适用性
core: indium
reagent type: catalyst
浓度
~39% In
杂质
2-3 mol/mol water
SMILES字符串
O.Cl[In](Cl)Cl
InChI
1S/3ClH.In.H2O/h3*1H;;1H2/q;;;+3;/p-3
InChI key
KYCHGXYBBUEKJK-UHFFFAOYSA-K
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应用
Reagent/catalyst for various organic transformations, e.g. allylation of aldehydes, ketones, and quinones; Diels-Alder reaction; the aldol reaction; Michael additions; the reductive Friedel-Crafts;
警示用语：
Danger
危险声明
危险分类
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation
靶器官
Lungs
储存分类代码
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
Loh, T.-P.; Li, X.-R.,
Angewandte Chemie (International Edition in English), 36, 980-980 (1997)
Reddy, B. G.; Kumareswaran, R. et al.
Tetrahedron Letters, 41, 10333-10333 (2000)
Chapman, C. J.; Frost, C. G. et al.
Tetrahedron Letters, 42, 773-773 (2001)
S Kobayashi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 6(19), 3491-3494 (2000-11-10)
Group 3-15 metal chlorides (Lewis acids) were classified on the basis of activity and aldehyde- and aldimine-selectivity in an addition reaction of a silyl enol ether. Based on the experimental results, metal chlorides (Lewis acids) were classified as follows: A
David S Giera et al.
Organic letters, 12(21), 4884-4887 (2010-10-01)
Allyl chlorides tethered to an N-aryl moiety readily undergo InCl(3)-catalyzed Friedel-Crafts reactions to furnish highly enantiomerically enriched 1,2,3,4-tetrahydroquinolines with good yields and excellent diastereoselectivity.
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