所有图片(1)
About This Item
线性分子式:
Zn(CH(CH3)2)2
CAS号:
分子量:
151.57
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
浓度
1.0 M in toluene
密度
0.895 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
CC(C)[Zn]C(C)C
InChI
1S/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3;
InChI key
KDUNMLRPPVCIGP-UHFFFAOYSA-N
应用
Diisopropylzinc is a general reagent used in the organic asymmetric synthesis such as the asymmetric synthesis of [6]?helicene, [5]-helicene and, enantiomerically enriched 5-pyrimidyl alkanol.
包装
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2
靶器官
Central nervous system, Respiratory system
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
23.0 °F - closed cup
闪点(°C)
-5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
易制毒化学品（3类）
Highly enantioselective synthesis of organic compound using right-and left-handed helical silica.
Sato, Itaru et al.
Tetrahedron Letters, 44(4), 721-724 (2003)
Asymmetric Synthesis of Chiral Secondary Alcohols with Isopropyl Substituents by the Catalytic Enantioselective Addition of Diisopropylzinc to Aldehydes Using N, N-Dialkylnorephedrines as Chiral Catalysts.
Soai, Kenso et al.
The Journal of Organic Chemistry, 59(25), 7908-7909 (1994)
Asymmetric induction by helical hydrocarbons:[6]-and [5] helicenes.
Sato, Itaru et al.
Angewandte Chemie (International Edition in English), 113(6), 1130-1132 (2001)
Stereoselective preparation and reactions of configurationally defined dialkylzinc compounds.
Boudier, Andreas et al.
Chemistry?A European Journal , 6(15), 2748-2761 (2000)
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