所有图片(1)
About This Item
线性分子式:
Zn(CH(CH3)2)2
CAS号:
分子量:
151.57
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
浓度
1.0 M in toluene
密度
0.895 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
CC(C)[Zn]C(C)C
InChI
1S/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3;
InChI key
KDUNMLRPPVCIGP-UHFFFAOYSA-N
应用
Diisopropylzinc is a general reagent used in the organic asymmetric synthesis such as the asymmetric synthesis of [6]?helicene, [5]-helicene and, enantiomerically enriched 5-pyrimidyl alkanol.
包装
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2
靶器官
Central nervous system, Respiratory system
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
23.0 °F - closed cup
闪点(°C)
-5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
易制毒化学品（3类）
危险化学品
Asymmetric Synthesis of Chiral Secondary Alcohols with Isopropyl Substituents by the Catalytic Enantioselective Addition of Diisopropylzinc to Aldehydes Using N, N-Dialkylnorephedrines as Chiral Catalysts.
Soai, Kenso et al.
The Journal of Organic Chemistry, 59(25), 7908-7909 (1994)
Stereoselective preparation and reactions of configurationally defined dialkylzinc compounds.
Boudier, Andreas et al.
Chemistry?A European Journal , 6(15), 2748-2761 (2000)
Highly enantioselective synthesis of organic compound using right-and left-handed helical silica.
Sato, Itaru et al.
Tetrahedron Letters, 44(4), 721-724 (2003)
Asymmetric induction by helical hydrocarbons:[6]-and [5] helicenes.
Sato, Itaru et al.
Angewandte Chemie (International Edition in English), 113(6), 1130-1132 (2001)
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