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551112

Sigma-Aldrich

红荧烯

sublimed grade, 99.99% trace metals basis

别名:

5,6,11,12-四苯基并四苯

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About This Item

经验公式（希尔记法）:
C42H28
CAS号:
517-51-1
分子量:
532.67
Beilstein:
1917339
EC 号:
208-242-0
MDL编号:
MFCD00003703
UNSPSC代码:
12352103
PubChem化学物质编号:
24879199
NACRES:
NA.23

等级

sublimed grade

质量水平

100

方案

99.99% trace metals basis

mp

330-335 °C (lit.)

λmax

299 nm
299 nm

荧光

λem 550 nm in THF

轨道能量

HOMO 5.4 eV 
LUMO 3.2 eV 

OLED设备性能

ITO/CuPc/NPD/Alq3:Rubrene (5%): DCM2 (2%)/Alq3/Mg:In

  • Color: red
  • Max. Luminance: 7780 Cd/m2

ITO/PEDOT:PSS/EHCz:Rubrene (1 wt%)/Cs2CO3:ITO
  • Color: red
  • Max. EQE: 0.03 %

SMILES字符串

c1ccc(cc1)-c2c3ccccc3c(-c4ccccc4)c5c(-c6ccccc6)c7ccccc7c(-c8ccccc8)c25

InChI

1S/C42H28/c1-5-17-29(18-6-1)37-33-25-13-14-26-34(33)39(31-21-9-3-10-22-31)42-40(32-23-11-4-12-24-32)36-28-16-15-27-35(36)38(41(37)42)30-19-7-2-8-20-30/h1-28H

InChI key

YYMBJDOZVAITBP-UHFFFAOYSA-N

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相关类别

一般描述

根据要求可进行 TGA/DSC 指定批次追溯

应用

可用作 OLED 掺杂剂（红色，λem = 550nm）和 p 型有机半导体的有机电子材料。在基于升华红荧烯单晶的有机场效应晶体管中，载流子迁移率可达 8-20cm2/Vs。
用于化学发光研究和过渡金属络合物形成的试剂。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

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分析证书(COA)

Lot/Batch Number
0000299443
0000299443
0000141324
0000157898
0000157898

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Morpurgo, A. F. et al.
Physica Status Solidi (A): Applied Research, 201, 1302-1302 (2004)
Alexander S Bieber et al.
The Journal of chemical physics, 153(8), 084703-084703 (2020-09-03)
Triplet-triplet annihilation-based photon upconversion (UC) using bulk perovskite sensitizers has been previously shown to facilitate efficient UC at low fluences. However, the fabrication of the UC devices has not been fully optimized; thus, there is room for improvement. Here, we
N R Armstrong et al.
Annual review of physical chemistry, 52, 391-422 (2001-04-28)
Electrochemical processes leading to light emission are reviewed, with emphasis on aspects of this subject relevant to the understanding and optimization of electrogenerated luminescence (EL) in organic thin-film materials. The basic energetic requirements of light emission from electrochemically initiated solution
V Podzorov et al.
Physical review letters, 95(22), 226601-226601 (2005-12-31)
We have observed the Hall effect in the field-induced accumulation layer on the surface of single-crystal samples of a small-molecule organic semiconductor rubrene. The Hall mobility muH increases with decreasing temperature in both the intrinsic (high-temperature) and trap-dominated (low-temperature) conduction
Rui M Pinto et al.
Journal of the American Chemical Society, 137(22), 7104-7110 (2015-05-21)
Exciton diffusion is at the heart of most organic optoelectronic devices' operation, and it is currently the most limiting factor to their achieving high efficiency. It is deeply related to molecular organization, as it depends on intermolecular distances and orbital
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