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About This Item
线性分子式:
[(CH3)3C]2SiH2
CAS号:
分子量:
144.33
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
方案
97%
折射率
n20/D 1.42 (lit.)
沸点
129-130 °C (lit.)
mp
−38 °C (lit.)
密度
0.729 g/mL at 25 °C (lit.)
SMILES字符串
[H][Si]([H])(C(C)(C)C)C(C)(C)C
InChI
1S/C8H20Si/c1-7(2,3)9-8(4,5)6/h9H2,1-6H3
InChI key
ZLKSBZCITVUTSN-UHFFFAOYSA-N
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应用
Di-tert-butylsilane can be used as a reagent to synthesize:
- 1,1-di-tert-butyl-N-phenylsilanamine by dehydrogenative coupling with aniline in the presence of supported gold catalyst.
- Benzyloxy di-tert-butylsilane by dehydrocoupling of benzyl alcohol using NaOH as a catalyst.
- Di-tert-butyl(3-cyclohexylprop-1-yn-1-yl)silane by silylation reaction with 2-propyn-1-ylcyclohexane using alkali metal hydroxide as a catalyst.
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
28.0 °F - closed cup
闪点(°C)
-2.22 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Sodium Hydroxide Catalyzed Dehydrocoupling of Alcohols with Hydrosilanes
Toutov AA, et al.
Organic Letters, 18(22), 5776-5779 (2016)
Alkali metal-hydroxide-catalyzed C (sp)-H bond silylation
Toutov AA, et al.
Journal of the American Chemical Society, 139(4), 1668-1674 (2017)
Dehydrogenative Coupling of Hydrosilanes with Amines Using Au/HAP
Uozumi Y and Hamasaka G
Synfacts, 11(05), 0558-0558 (2015)
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