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Merck
CN

526274

Sigma-Aldrich

5-氟水杨醛

97%

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别名:
5-氟-2-羟基苯甲醛
线性分子式:
FC6H3(OH)CHO
CAS号:
分子量:
140.11
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

mp

82-85 °C (lit.)

SMILES字符串

Oc1ccc(F)cc1C=O

InChI

1S/C7H5FO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H

InChI key

FDUBQNUDZOGOFE-UHFFFAOYSA-N

一般描述

5-Fluorosalicylaldehyde can be synthesized from 4-fluorophenol.

应用

5-Fluorosalicylaldehyde may be used to synthesize:
  • managanese (III) complex [MnLa1,3-N3)]n [H2La = N,N′-bis(5-fluorosalicylidene)-1,2-diaminoethane]
  • enantiopure 4-amino-6-fluoro-3-(hydroxymethyl)chromanes
  • 4,4′-difluoro-2,2′-[(hydrazine-1,2-diylidene)bis(methanylylidene)]-diphenol
  • N,N′-bis(5-fluoro-2-hydroxybenzylidene)ethylenediamine
  • N,N′-(2-hydroxypropane-1,3-diyl)-bis(salicylaldimine (H2L)

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Synthesis and crystal structure of a novel tri-nuclear nickel (II) complex derived from N, N'-(2-hydroxypropane-1, 3-diyl) bis (salicylaldimine).
Cui YM, et al.
Russian Journal of Coordination Chemistry, 40(10), 768-772 (2014)
Synthesis, Characterization and Crystal Structures of N, N'-bis (5-Fluoro-2-hydroxybenzylidene)-ethylenediamine and 4, 4'-Difluoro-2, 2'-[(hydrazine-1, 2-diylidene) bis (methanylylidene)] diphenol.
Zhang WM, et al.
Asian Journal of Chemistry, 26(22), 7843-7843 (2014)
Large perturbations of long-range n J (1H, 1H) and n J (1H, 19F) by the intramolecular hydrogen bonds in 2-mercaptobenzaldehyde, salicylaldehyde, and some derivatives. Reference structures for intramolecular hydrogen bonds.
Schaefer T, et al.
Canadian Journal of Chemistry, 71(7), 960-967 (1993)
Synthesis of Enantiopure 4-Amino-6-fluoro-3-(hydroxymethyl) chromanes via Intramolecular Nitrone Cycloadditions.
Broggini G, et al.
J. Chem. Res. Synop., 2, 36-37 (1997)
Manganese (III) complexes derived from bis-Schiff bases: Synthesis, structures, and antimicrobial activity.
Liu QR, et al.
Russian Journal of Coordination Chemistry, 40(10), 757-763 (2014)

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