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518751

4-氨基苯基硼酸频哪醇酯

Name: 4-氨基苯基硼酸频哪醇酯
Brand: ALDRICH

97%

别名:

4-(4,4,5,5-四甲基-1,3,2-二氧杂硼烷-2-基)苯胺, 4-氨基苯基硼酸频哪醇环酯

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About This Item

经验公式（希尔记法）:

C₁₂H₁₈BNO₂

CAS号:

214360-73-3

分子量:

219.09

MDL编号:

MFCD02093721

UNSPSC代码:

12352103

PubChem化学物质编号:

24874043

NACRES:

NA.22

质量水平

100

检测方案

97%

mp

165-169 °C (lit.)

SMILES字符串

CC1(C)OB(OC1(C)C)c2ccc(N)cc2

InChI

1S/C12H18BNO2/c1-11(2)12(3,4)16-13(15-11)9-5-7-10(14)8-6-9/h5-8H,14H2,1-4H3

InChI key

ZANPJXNYBVVNSD-UHFFFAOYSA-N

应用

4-氨基苯硼酸频哪醇酯可用作反应物制备：

通过与碘代色酮进行钯催化的Suzuki-Miyaura交叉偶联反应制备取代3-苯基-4H-1-苯并吡喃-4-酮。
利用基于从五醌到罗丹明通过键的能量转移的荧光指示剂、通过荧光测定法检测汞（II）。
铑催化的胺化反应。
钯催化的Suzuki交叉偶联以合成潜在的抗结核和抗微生物化合物。

它也可用于制备：

六苯基苯衍生物，作为一种潜在的生物探针和多通道键盘系统
基于均苯四甲酸二酰亚胺的聚合物，作为溶液可处理的n-通道场效应晶体管的基质
低聚亚芳基和萘双酰亚胺，作为低带隙半导体的替代共聚物，具有电化学和光谱电化学行为
γ用于治疗淀粉样蛋白β形成的分泌酶调节剂

象形图

GHS07

警示用语：

Warning

危险声明

H315,H319,H335

预防措施声明

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Suzuki-Miyaura cross-coupling reaction on copper-trans-A(2)B corroles with excellent functional group tolerance.

Michael König et al.

Tetrahedron, 67(23), 4243-4252 (2011-07-16)

The palladium-catalyzed Suzuki-Miyaura cross-coupling reaction has been investigated on meso-substituted trans-A(2)B-corrole using tailored Pd-catalyst systems.We present the first examples of Suzuki-Miyaura cross-coupling reactions on meso-substituted trans-A(2)B-corrole derivatives with neutral, sterically hindered, inactivated and heteroaromatic boronic acids and esters, alkenylboronic acids

Structural studies on bioactive compounds. 40.(1) Synthesis and biological properties of fluoro-, methoxyl-, and amino-substituted 3-phenyl-4H-1-benzopyran-4-ones and a comparison of their antitumor activities with the activities of related 2-phenylbenzothiazoles.

David A Vasselin et al.

Journal of medicinal chemistry, 49(13), 3973-3981 (2006-06-23)

A new series of fluoro-, methoxyl-, and amino-substituted isoflavones have been synthesized as potential antitumor agents based on structural similarities to known flavones and isoflavones (quercetin and genistein respectively) and antitumor 2-phenylbenzothiazoles. Target compounds were synthesized using palladium-catalyzed coupling methodologies

Aminothiazoles as γ-secretase modulators

Luebbers, T.; et al.

Bioorganic & Medicinal Chemistry Letters, 21, 6554-6558 (2012)

Recognition of adenosine monophosphate and H2PO4- using zinc ensemble of new hexaphenylbenzene derivative: potential bioprobe and multichannel keypad system.

Vandana Bhalla et al.

Organic letters, 14(4), 1012-1015 (2012-01-28)

Zinc ensemble of hexaphenylbenzene derivative 3 exhibits sensitive response toward adenosine monophosphate (AMP) and H(2)PO(4)(-) ions. Further, the application of derivative 3 as a multichannel molecular keypad could be realized in the presence of inputs of Zn(2+) ions, H(2)PO(4)(-) ions

Synthesis and Characterization of a Pyromellitic Diimide-Based Polymer with C- and N-Main Chain Links: Matrix for Solution-Processable n-Channel Field-Effect Transistors

Kola, S.; et al.

ACS Macro Letters, 1, 136-140 (2012)

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