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Merck
CN

517003

乙酰丙酮铁 III

greener alternative

≥99.9% trace metals basis

别名:

2,4-戊二酮 铁(III) 衍生物, 2，4-戊二酮铁（III）, Fe(acac)3, 乙酰丙酮铁

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关于此项目

线性分子式:
Fe(C5H7O2)3
化学文摘社编号:
14024-18-1
分子量:
353.17
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24873913
EC Number:
237-853-5
Beilstein/REAXYS Number:
4157960
MDL number:
MFCD00000020

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产品名称

乙酰丙酮铁 III, ≥99.9% trace metals basis

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: iron
reagent type: catalyst

Quality Level

100

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

180-182 °C (dec.) (lit.)

density

5.24 g/mL at 25 °C (lit.)

greener alternative category

Aligned

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相关类别

Application

用于高结晶（Zn，Fe）Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。
三（乙酰丙酮）铁（Ⅲ）可用于：     
  • 通过强力纺丝（forcespinning ）技术合成Fe3O4//碳复合纤维的铁前体。这种复合材料用于形成锂离子电池的高性能阳极材料。      
  • 一种合成含铁金属有机框架（MOF）的前体，该有机框架用于可充电碱离子电池。   
  • 一种提高氧化过程中异丙苯N-羟基邻苯二甲酰亚胺（NHPI）催化剂效率的添加剂。     
  • 用于反渗透（RO）应用的聚酰胺膜制造中的溶剂活化剂。     
  • 用于高结晶（Zn，Fe）Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。乙酰丙酮铁（III）可用作合成水溶性磁铁矿纳米颗粒的前体，这种纳米颗粒可以应用于磁热治疗。      
  • 用于高结晶（Zn，Fe）Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。

General description

乙酰丙酮铁（III），也称为三（乙酰丙酮）铁（Ⅲ）或被，是一种配位化合物，可用作氧化铁纳米颗粒和薄膜合成的前体，这些纳米颗粒和薄膜在磁性材料、催化和电子应用中很重要。此外，它也被用作各种有机反应（包括聚合过程和交联反应）的催化剂。

Features and Benefits

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ9083
MKCX8828
0000382208
0000382208
0000269341

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Polymorphous transformations of nanometric iron (III) oxide: a review.
Zboril R, et al.
Chemistry of Materials, 23.14, 3255-3272 (2011)
Studies of magnetite nanoparticles synthesized by thermal decomposition of iron (III) acetylacetonate in tri(ethylene glycol)
Maity D, et al.
Journal of magnetism and magnetic materials, 321(19), 3093-3098 (2009)
Selective Detection of Iron (III) by Rhodamine-Modified Fe3O4 Nanoparticles.
Baodui, et al.
Angewandte Chemie (International Edition in English), 49.27, 4576-4579 (2010)
Arreerat Jiamprasertboon et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(48), 11337-11345 (2019-06-27)
Type I heterojunction films of α-Fe2 O3 /ZnO are reported here as a non-titania based photocatalyst, which shows remarkable enhancement in the photocatalytic properties towards stearic acid degradation under UVA-light exposure (λ=365 nm), with a quantum efficiency of ξ=4.42±1.54×10-4 molecules degraded/photon, which
Hyun-Uk Park et al.
Ultrasonics sonochemistry, 58, 104673-104673 (2019-09-27)
In this work, we introduce composition-tunable core-shell-like PdM@Pt (M = Mn and Fe) nanoparticles (NPs) on carbon support (PdM@Pt/C) synthesized by one-pot sonochemical reactions using high-intensity ultrasonic probe (150 W, 20 kHz, with 13 mm solid probe) and investigate their electrocatalytic performance for oxygen reduction
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