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Merck
CN

481718

五羰基铁

greener alternative

>99.99% trace metals basis

别名:

五羰基铁, 羰基铁

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关于此项目

线性分子式:
Fe(CO)5
化学文摘社编号:
13463-40-6
分子量:
195.90
NACRES:
NA.23
PubChem Substance ID:
24871777
UNSPSC Code:
12352103
EC Number:
236-670-8
MDL number:
MFCD00011001

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产品名称

五羰基铁, >99.99% trace metals basis

InChI key

FYOFOKCECDGJBF-UHFFFAOYSA-N

InChI

1S/5CO.Fe/c5*1-2;

SMILES string

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

vapor density

6.74 (vs air)

vapor pressure

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

assay

>99.99% trace metals basis

form

liquid

autoignition temp.

122 °F

reaction suitability

core: iron
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

density

1.49 g/mL at 25 °C (lit.)

greener alternative category

, Aligned

storage temp.

2-8°C

Quality Level

100

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相关类别

Application

用作以下过程的反应物：
  • 加成反应
  • 通过光解分解
  • 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
  • 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备

  • 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体
Chemical Synthesis of Monodisperse Magnetic Nanoparticles
Iron(0) pentacarbonyl can be used:
  • To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
  • As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
  • To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.

General description

Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

5.0 °F - closed cup

flash_point_c

-15 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBT3898
SHBS9620
SHBQ5322
SHBP3771
SHBQ1798

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R A Toshkova et al.
Journal of ethnopharmacology, 109(3), 394-399 (2006-09-19)
A purified saponin mixture (PSM) from Astragalus corniculatus Bieb. protected significantly hamsters against the experimental Graffi myeloid tumor. The application of PSM increased the survival rates, prolonged mean survival time and the tumor growth was markedly reduced. A purified saponin
Miguel D Ferrer et al.
The British journal of nutrition, 103(1), 69-76 (2009-11-04)
Our aim was to analyse the influence of variegate porphyria (VP) on the antioxidant defenses and markers of oxidative damage and inflammation in plasma and neutrophils and the effects of dietary supplementation with vitamins E and C on these parameters
Caixia Zhan et al.
Dalton transactions (Cambridge, England : 2003), 39(46), 11255-11262 (2010-10-23)
By using "click" chemistry between a diazide and a diiron model complex armed with two alkynyl groups, two polymeric diiron complexes (Poly-Py and Poly-Ph) were prepared. The two polymeric complexes were investigated using infrared spectroscopy, scanning electron microscopy (SEM), transmission
Ioan Silaghi-Dumitrescu et al.
Journal of the American Chemical Society, 130(3), 901-906 (2008-01-01)
Density functional theory studies on a series of Fe2(CO)6(PX)2 derivatives show the tetrahedrane to be the most stable for the alkyl (X = Me, tBu), P-H (X = H), and chloro (X = Cl) derivatives. However, butterfly diradical and planar
H Ohoyama et al.
The journal of physical chemistry. A, 115(40), 10888-10893 (2011-09-13)
The atomic alignment effect has been studied for the dissociative energy transfer reaction of metal carbonyls (Fe(CO)(5), Ni(CO)(4)) with the oriented Ar ((3)P(2), M(J) = 2). The emission intensity from the excited metal products (Fe*, Ni*) has been measured as
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