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安全信息

481718

Sigma-Aldrich

五羰基铁

greener alternative

>99.99% trace metals basis

别名:

五羰基铁, 羰基铁

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About This Item

线性分子式:
Fe(CO)5
CAS号:
13463-40-6
分子量:
195.90
EC 号:
236-670-8
MDL编号:
MFCD00011001
UNSPSC代码:
12352103
PubChem化学物质编号:
24871777
NACRES:
NA.23

蒸汽密度

6.74 (vs air)

质量水平

100

蒸汽压

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

方案

>99.99% trace metals basis

表单

liquid

自燃温度

122 °F

反应适用性

core: iron
reagent type: catalyst

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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折射率

n20/D 1.5196 (lit.)

沸点

103 °C (lit.)

mp

−20 °C (lit.)

密度

1.49 g/mL at 25 °C (lit.)

环保替代产品分类

, Aligned

储存温度

2-8°C

SMILES字符串

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

InChI key

FYOFOKCECDGJBF-UHFFFAOYSA-N

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一般描述

Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

用作以下过程的反应物：
  • 加成反应
  • 通过光解分解
  • 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
  • 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备

  • 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体
Chemical Synthesis of Monodisperse Magnetic Nanoparticles
Iron(0) pentacarbonyl can be used:
  • To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
  • As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
  • To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.

象形图

FlameSkull and crossbones
GHS02,GHS06

警示用语：

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

5.0 °F - closed cup

闪点(°C)

-15 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number
SHBQ5322
SHBP3771
SHBQ1798
SHBN5572
SHBM9102

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Kyoko Hibi et al.
Analytical and bioanalytical chemistry, 391(4), 1147-1152 (2008-04-29)
Bacterial cold water disease, caused by Flavobacterium psychrophilum, is a serious problem in the aquaculture industry worldwide. Several methods to prevent and treat cold water disease have been studied. Although detection at the early stage of F. psychrophilum infection is
Pro-oxidants or anti-oxidant defenses? Which one to blame in non-alcoholic steatohepatitis pathogenesis?
Isabelle A Leclercq
Journal of gastroenterology and hepatology, 27(11), 1651-1653 (2012-10-31)
Li Long et al.
Dalton transactions (Cambridge, England : 2003), 41(31), 9482-9492 (2012-07-04)
Reaction of Fe(3)(CO)(12) with pyridinyl thioester ligand PyCH(2)SCOCH(3) (L(1), Py = pyridin-2-yl) produced complex, [Fe(2)(κ-COCH(3))(μ-SCH(2)Py)(CO)(5)] (1) (PyCH(2)S = pyridin-2-ylmethanethiolate). When complex 1 reacted with PPh(3), a monosubstituted complex, [Fe(2)(κ-COCH(3))(μ-SCH(2)Py)(CO)(4)PPh(3)] (2), was derived. Reaction of the same precursor with analogous thioester
Brian Ahr et al.
Physical chemistry chemical physics : PCCP, 13(13), 5590-5599 (2011-01-15)
Ultrafast X-ray absorption near edge spectroscopy has been carried out for photo excited iron pentacarbonyl in ethanol with 2 picosecond resolution. A temporal resolution limited dissociation process was observed, followed by the formation of the mono-substituted complex Fe(CO)(4)EtOH within a
J L Arias et al.
International journal of pharmaceutics, 339(1-2), 237-245 (2007-04-03)
A reproducible method for the preparation of mixed colloidal nanoparticles, consisting of a magnetic carbonyl iron nucleus and a biocompatible ethylcellulose latex shell, is described in this article. The heterogeneous structure of the particles can confer them both the possibility
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