所有图片(1)
About This Item
线性分子式:
(C6H11)2PCl
CAS号:
分子量:
232.73
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.533 (lit.)
沸点
165 °C/12 mmHg (lit.)
密度
1.054 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
ClP(C1CCCCC1)C2CCCCC2
InChI
1S/C12H22ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChI key
AKJFBIZAEPTXIL-UHFFFAOYSA-N
应用
二环己基氯化膦可用作反应物参与合成：
它还可用作原料制备其他配体，如二环己基氧化膦、膦基取代的N-芳基吡咯 、二叔丁基（（二环己基膦基）甲基）膦 、二环己基环戊基膦。这些配体可用于钯催化的交叉偶联反应。
- 1,2-双（二环己基次膦氧基）乙烷配体（在存在三乙胺的情况下与乙二醇通过Michaelis−-Arbuzov重排反应）。
- 1,1,2,2-四环己基二膦一硫化物配体（通过LiS处理）。
它还可用作原料制备其他配体，如二环己基氧化膦、膦基取代的N-芳基吡咯 、二叔丁基（（二环己基膦基）甲基）膦 、二环己基环戊基膦。这些配体可用于钯催化的交叉偶联反应。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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