所有图片(1)
About This Item
线性分子式:
SnCl2 · 2H2O
CAS号:
分子量:
225.65
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
≥99.97% trace metals basis
反应适用性
core: tin
reagent type: catalyst
沸点
652 °C (lit.)
mp
37-38 °C (dec.) (lit.)
SMILES字符串
O.O.Cl[SnH2]Cl
InChI
1S/2ClH.2H2O.Sn/h2*1H;2*1H2;/q;;;;+2/p-2
InChI key
FWPIDFUJEMBDLS-UHFFFAOYSA-L
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应用
氯化锡（II）二水合物可作为温和的路易斯酸催化剂用于合成：
它也可作为助催化剂，用于在钌催化剂存在的情况下以三乙醇胺处理苯胺来合成吲哚衍生物。
- 通过芳族醛、2-氨基吡啶和异腈的三组分缩合反应制备的3-氨基咪唑并[1,2-a]吡啶。
- 通过5-氨基-3-（芳基氨基）-1H-吡唑-4-甲腈与环己烷-1,3-二酮或双甲酮的环缩合反应制备的吡唑[5,4-b]喹啉衍生物。
- 在琥珀酸酐存在的情况下由乳酸水溶液制备的聚乳酸。
它也可作为助催化剂，用于在钌催化剂存在的情况下以三乙醇胺处理苯胺来合成吲哚衍生物。
警示用语：
Danger
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
靶器官
Cardio-vascular system, Respiratory system
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Jonathan J Gridley et al.
Chemical communications (Cambridge, England), (20), 2550-2551 (2003-11-05)
Condensations between the tin(II) enolate 11 of ethyl N-tosylglycinate and conjugated ynals 12 and ynones 14 are highly diastereoselective, in favour of the anti-isomers 13 and 15; similar reactions of enals and enones 17 show lower but still useful levels
Xiang-Hui Tan et al.
Organic letters, 5(11), 1833-1835 (2003-05-24)
[reaction: see text] Under the Lewis acid catalysis offered by TiCl(3), SnCl(2) can efficiently mediate the aqueous Barbier reactions between aldehydes and allyl chloride or bromide.
Ji A Hong et al.
ACS applied materials & interfaces, 12(2), 2417-2423 (2019-12-21)
Tin oxide (SnO2) is widely adopted as an electron transport layer in perovskite solar cells (PeSCs) because it has high electron mobility, excellent charge selective behavior owing to a large band gap of 3.76 eV, and low-temperature processibility. To achieve
Jianfei Huang et al.
ACS nano, 15(1), 1753-1763 (2021-01-14)
Continuously enhanced photoresponsivity and suppressed dark/noise current combinatorially lead to the recent development of high-detectivity organic photodetectors with broadband sensing competence. Despite the achievements, reliable photosensing enabled by organic photodetectors (OPDs) still faces challenges. Herein, we call for heed over
Sharp, S.L. et al.
Chemistry of Materials, 10, 880-880 (1998)
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