Novel carbonyl allylation mediated by SnCl2/TiCl3 in water.

Novel carbonyl allylation mediated by SnCl2/TiCl3 in water.

Organic letters (2003-05-24)

Xiang-Hui Tan, Bo Shen, Wei Deng, Hui Zhao, Lei Liu, Qing-Xiang Guo

摘要

[reaction: see text] Under the Lewis acid catalysis offered by TiCl(3), SnCl(2) can efficiently mediate the aqueous Barbier reactions between aldehydes and allyl chloride or bromide.

材料

货号

品牌

产品描述

474762

Sigma-Aldrich

氯化锡(II) 二水合物, ≥99.97% trace metals basis