471933
4-碘苯硼酸
≥95.0%
别名:
B-(4-iodophenyl)-boronic acid, p-Iodophenylboronic acid, p-iodo-benzeneboronic acid
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关于此项目
线性分子式:
IC6H4B(OH)2
化学文摘社编号:
分子量:
247.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
4-碘苯硼酸, ≥95.0%
InChI
1S/C6H6BIO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
SMILES string
OB(O)c1ccc(I)cc1
InChI key
PELJYVULHLKXFF-UHFFFAOYSA-N
assay
≥95.0%
mp
326-330 °C (lit.)
functional group
iodo
Quality Level
Application
试剂用于
试剂用于制备
- 铜介导的无配体好氧氟烷基化
- 钯催化的好氧氧化交叉偶联反应
- 用于 Suzuki 偶联反应的可回收磁性纳米离子负载的钯催化剂
- 使用铜（Cu）催化剂的氧化羟基化
- 无配体钯催化的 Suzuki-Miyaura 交叉偶联
- 使用金盐催化剂的同型偶联
- 钌（Ru）催化的交叉偶联
- CuI 催化的 Suzuki 偶联反应
- 钯催化的多米诺骨牌 Heck-Mizoroki/Suzuki-Miyaura 反应
- 三乙酸锰介导的芳基硼酸向烯烃的自由基加成
试剂用于制备
- 通过“点击化学”策略合成截短侧耳素衍生物，进行用于研究与核糖体结合和抗菌活性
- 液晶聚乙炔衍生物
Other Notes
含不定量的酸酐
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions of organoboronic acids with alkynyl bromides
X. Zhang, et al.,
Synthesis, 18, 2975-2983 (2011)
Samir Yahiaoui et al.
The Journal of organic chemistry, 76(8), 2433-2438 (2011-03-23)
A palladium(II)-catalyzed Heck-Mizoroki/Suzuki-Miyaura domino reaction involving metal coordinating dimethylaminoethyl vinyl ethers and a number of electron-rich and electron-deficient arylboronic acids has been developed. Through variation of the temperature and the concentration of the p-benzoquinone (p-Bq) ligand/reoxidant, conditions for the robust
Hong Li et al.
Chemical communications (Cambridge, England), 47(27), 7880-7882 (2011-06-11)
The first ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids is reported. Various aliphatic and aromatic aldehydes are transformed to the corresponding arylketones. A total of 31 examples with moderate to excellent yields are presented, together with the results of an
Arne Dickschat et al.
Organic letters, 12(18), 3972-3974 (2010-08-20)
Arylboronic acids are shown to be valuable precursors for aryl radicals upon treatment with manganese triacetate. Under these oxidative conditions the intermediately generated aryl radicals undergo addition to olefins to give the arylhydroxylation products A in the presence of dioxygen.
Homocoupling of arylboronic acids catalyzed by simple gold salts
Matsuda, T.; et al.
Tetrahedron, 52, 4779-4781 (2011)
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