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安全信息

469858

Sigma-Aldrich

四(二甲基胺基)钛(IV)

99.999% trace metals basis

别名:

TDMAT, 四(二甲基氨基)钛(IV)

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About This Item

线性分子式:
[(CH3)2N]4Ti
CAS号:
3275-24-9
分子量:
224.17
EC 号:
221-904-3
MDL编号:
MFCD00014861
UNSPSC代码:
12352103
PubChem化学物质编号:
24870618
NACRES:
NA.23

质量水平

200

检测方案

99.999% trace metals basis

形式

liquid

反应适用性

core: titanium

bp

50 °C/0.5 mmHg (lit.)

密度

0.947 g/mL at 25 °C (lit.)

SMILES字符串

CN(C)[Ti](N(C)C)(N(C)C)N(C)C

InChI

1S/4C2H6N.Ti/c4*1-3-2;/h4*1-2H3;/q4*-1;+4

InChI key

MNWRORMXBIWXCI-UHFFFAOYSA-N

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一般描述

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应用

Tetrakis（二甲基氨基）钛（IV）（TDMAT）是通过有机金属化学气相沉积（OMCVD）和通过原子层沉积（ALD）的二氧化钛薄膜的氮化钛（TiN）薄膜的前体。TDMAT 与过量的环戊二烯发生放热反应得到三（二甲基氨基）（η5-环戊二烯基）钛（IV）。

象形图

FlameCorrosion
GHS02,GHS05

警示用语：

Danger

危险声明

H225,H260,H314

危险分类

Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

补充剂危害

EUH014

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Chemistry of Materials, 8, 2712-2712 (1996)
Science of Synthesis: Organometallic Complexes of Titanium
Mikami K, et al. et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 494-494 (2014)
Improving performance via blocking layers in dye-sensitized solar cells based on nanowire photoanodes.
Li L, et al.
ACS Applied Materials & Interfaces, 7(23), 12824-12831 (2015)
Degao Wang et al.
Proceedings of the National Academy of Sciences of the United States of America, 115(34), 8523-8528 (2018-08-08)
Stabilized photoanodes for light-driven water oxidation have been prepared on nanoparticle core/shell electrodes with surface-stabilized donor-acceptor chromophores, a water oxidation catalyst, and an electron-transfer mediator. For the electrode, fluorine-doped tin oxide FTO|SnO2/TiO2|-Org1-|1.1 nm Al2O3|-RuP2+-WOC (water oxidation catalyst) with Org1 (1-cyano-2-(4-(diphenylamino)phenyl)vinyl)phosphonic
Young modulus and Poisson ratio measurements of TiO 2 thin films deposited with atomic layer deposition.
Borgese L, et al.
Surface and Coatings Technology, 206(8), 2459-2463 (2012)
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