所有图片(2)
别名:
4-(二羟基硼烷基)苯甲酸, 4-硼酸苯甲酸, 4-羟基羰基苯基硼酸, 4-羧基苯基硼酸, 4-羧基苯硼酸, NSC 221170, 对硼酸苯甲酸, 对羧基苯基硼酸, 对羧基苯硼酸
线性分子式:
HO2CC6H4B(OH)2
CAS号:
分子量:
165.94
Beilstein:
3031088
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
EC索引号:
604-189-6
NACRES:
NA.22
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质量水平
mp
220 °C (dec.) (lit.)
SMILES字符串
OB(O)c1ccc(cc1)C(O)=O
InChI
1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)
InChI key
SIAVMDKGVRXFAX-UHFFFAOYSA-N
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应用
作为反应物参与：
- 与聚苯乙烯胶乳表面稳定链的缩合反应
- Suzuki偶联反应
- 酯化
- 聚乙烯胺衍生化
- 同位素标记汞的合成
- 聚SiNW官能化用于检测多巴胺
作为试剂用于
作为试剂用于
- Suzuki-Miyaura交叉偶联反应
- NIR荧光染料诱导的pH敏感度对量子点荧光寿命的影响
- 生物负载的钯纳米颗粒，作为水中Suzuki反应的无磷催化剂
- 在室温下与芳基硼酸一起进行Chan-Lam型铜（Cu）催化的S-芳基化
作为试剂用于
- 通过区域选择性Suzuki-Miyaura交叉偶联反应结合钯催化的分子内氨基羰基化和环化反应制备异喹啉酮
- 制备安普那韦基P1取代双芳基衍生物，是超有效的HIV-1蛋白酶抑制剂
- 以空气为氧化剂，通过可见光引发、钌（Ru）-配合物催化的芳基硼酸有氧氧化羟基化反应制备苯酚
- 葡萄糖敏感性含硼嵌段共聚物
- 制备三磺化杯芳烃上层磺酰胺基衍生物及其与三甲基赖氨酸表观遗传标记的配合物
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Hai Wang et al.
Journal of colloid and interface science, 590, 103-113 (2021-02-02)
The self-healing mechanism and bioelectrochemical interface properties of supramolecular gels have been rarely explored. In this context, we propose a constitutive "fibril-reorganization" model to reveal the self-healing mechanism of a series of core-shell structured guanosine-borate (GB) hydrogels and emphasize that
Xiu Ye et al.
Nanomaterials (Basel, Switzerland), 9(5) (2019-05-10)
Aggregation-induced emission (AIE) active cellulose nanocrystals (TPE-CNCs) were synthesized by attaching tetraphenylethylene (TPE) to cellulose nanocrystals (CNCs). The structure and morphology of TPE-CNCs were characterized by FT-IR, XRD, ζ-potential measurements, elemental analysis, TEM, atomic force microscopy (AFM), and dynamic laser
Jae Kyoo Lee et al.
Proceedings of the National Academy of Sciences of the United States of America, 117(49), 30934-30941 (2020-11-25)
It was previously shown [J. K. Lee et al., Proc. Natl. Acad. Sci. U.S.A, 116, 19294-19298 (2019)] that hydrogen peroxide (H2O2) is spontaneously produced in micrometer-sized water droplets (microdroplets), which are generated by atomizing bulk water using nebulization without the
Maria Antonietta Casulli et al.
Small (Weinheim an der Bergstrasse, Germany), 16(44), e2003359-e2003359 (2020-10-10)
The aim of the present paper is to highlight a novel electrochemical assay for an extremely-selective detection of fructose thanks to the use of a supramolecular complex between β-cyclodextrins (β-CDs) and a chemically modified ferrocene with boronic acid named 4-Fc-PB/natural-β-CDs.
Rui Tang et al.
Journal of the American Chemical Society, 134(10), 4545-4548 (2012-03-01)
Modulation of the fluorescence lifetime (FLT) of CdTeSe/ZnS quantum dots (QDs) by near-IR (NIR) organic chromophores represents a new strategy for generating reproducible pH-sensing nanomaterials. The hybrid construct transfers the pH sensitivity of photolabile NIR cyanine dyes to highly emissive
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