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Merck
CN

452807

三氯(3,3,3-三氟丙基)硅烷

97%

别名:

三氟丙基三氯硅烷

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关于此项目

线性分子式:
CF3CH2CH2SiCl3
化学文摘社编号:
分子量:
231.50
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-744-2
Beilstein/REAXYS Number:
1748876
MDL number:
Assay:
97%
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InChI key

WEUBQNJHVBMUMD-UHFFFAOYSA-N

InChI

1S/C3H4Cl3F3Si/c4-10(5,6)2-1-3(7,8)9/h1-2H2

SMILES string

FC(F)(F)CC[Si](Cl)(Cl)Cl

assay

97%

refractive index

n20/D 1.386 (lit.)

bp

114 °C (lit.)

density

1.419 g/mL at 25 °C (lit.)

functional group

fluoro

Quality Level

Application

三氯(3,3,3-三氟丙基)硅烷可作为前体用于制备:
  • 通过碱催化的缩合反应制备氟化多面体倍半硅氧烷(F-POSS)。        
  • 通过与甲醇发生醇解反应制备3,3,3-三氟丙基三甲氧基硅烷。

它可作为硅烷化剂用于涂覆移液管的内表面以用于研究从微量移液管中排出的液滴的电荷。

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.7 °F - closed cup - (own results)

flash_point_c

45.4 °C - closed cup - (own results)

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Dongwhi Choi et al.
Scientific reports, 3, 2037-2037 (2013-06-21)
We report that a droplet dispensed from a micropipette almost always has a considerable electrical charge of a magnitude dependent on the constituents of the droplet, on atmospheric humidity and on the coating material of pipette tip. We show that
Scott T Iacono et al.
Chemical communications (Cambridge, England), (47), 4992-4994 (2007-12-01)
New fluorinated polyhedral oligomeric silsesquioxane (F-POSS) structures possessing a high degree of hydrophobicity have been prepared via a facile corner-capping methodology.
Journal of the Electrochemical Society, 142, L11-L11 (1995)
Alcoholysis synthesis of 3, 3, 3-trifluoropropyltrimethoxysilane by solvent method [J]
Biqian Jin
New Chemical Materials, 11 (2007)
Spontaneous electrical charging of droplets by conventional pipetting.
Scientific Reports, 3 (2013)

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