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Merck
CN

452807

Sigma-Aldrich

三氯(3,3,3-三氟丙基)硅烷

97%

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别名:
三氟丙基三氯硅烷
线性分子式:
CF3CH2CH2SiCl3
CAS号:
分子量:
231.50
Beilstein:
1748876
EC 号:
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

折射率

n20/D 1.386 (lit.)

bp

114 °C (lit.)

密度

1.419 g/mL at 25 °C (lit.)

SMILES字符串

FC(F)(F)CC[Si](Cl)(Cl)Cl

InChI

1S/C3H4Cl3F3Si/c4-10(5,6)2-1-3(7,8)9/h1-2H2

InChI key

WEUBQNJHVBMUMD-UHFFFAOYSA-N

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应用

三氯(3,3,3-三氟丙基)硅烷可作为前体用于制备:
  • 通过碱催化的缩合反应制备氟化多面体倍半硅氧烷(F-POSS)。        
  • 通过与甲醇发生醇解反应制备3,3,3-三氟丙基三甲氧基硅烷。

它可作为硅烷化剂用于涂覆移液管的内表面以用于研究从微量移液管中排出的液滴的电荷。

象形图

FlameCorrosion

警示用语:

Danger

危险声明

危险分类

Flam. Liq. 3 - Skin Corr. 1B

补充剂危害

WGK

WGK 3

闪点(°F)

113.7 °F

闪点(°C)

45.4 °C

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Scott T Iacono et al.
Chemical communications (Cambridge, England), (47), 4992-4994 (2007-12-01)
New fluorinated polyhedral oligomeric silsesquioxane (F-POSS) structures possessing a high degree of hydrophobicity have been prepared via a facile corner-capping methodology.
Dongwhi Choi et al.
Scientific reports, 3, 2037-2037 (2013-06-21)
We report that a droplet dispensed from a micropipette almost always has a considerable electrical charge of a magnitude dependent on the constituents of the droplet, on atmospheric humidity and on the coating material of pipette tip. We show that
Fabrication of Carbon Nanotube High-Frequency Nanoelectronic Biosensor for Sensing in High Ionic Strength Solutions
Journal of Visualized Experiments, 77, e50438-e50438 (2013)
Kyung Won Ro et al.
Electrophoresis, 24(18), 3253-3259 (2003-10-01)
Capillary electrochromatography (CEC) and preconcentration of neutral compounds have been realized on poly(dimethylsiloxane) (PDMS) microchips. The channels are coated with polyelectrolyte multilayers to avoid absorption of hydrophobic analytes into PDMS. The structures of a microchip include an injector and a
Shifted transfer characteristics of organic thin film and single crystal FETs.
Synt. Metals, 146(3), 325-328 (2004)

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