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产品线
AnhydroBeads™
质量水平
方案
99.999% trace metals basis
杂质
≤15.0 ppm Trace Metal Analysis
粒径
−10 mesh
mp
652 °C (lit.)
密度
2.98 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Mn]Cl
InChI
1S/2ClH.Mn/h2*1H;/q;;+2/p-2
InChI key
GLFNIEUTAYBVOC-UHFFFAOYSA-L
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应用
通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构,在基态时具有 24 个不成对电子。还用于形成可用于自由基环化反应的活性 Mn(0) 物质。
法律信息
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Danger
危险声明
危险分类
Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2
靶器官
Brain
储存分类代码
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
Jerome A Roth et al.
Toxicology in vitro : an international journal published in association with BIBRA, 26(7), 1143-1149 (2012-07-31)
Mutations in the parkin gene are linked to development of juvenile onset of Parkinson's disease and recent studies have reported that parkin can protect against increased oxidative stress and mitochondrial dysfunction caused by a variety of oxidative and toxic insults.
A G Kanthasamy et al.
Toxicology letters, 214(3), 288-295 (2012-09-22)
The role of normal cellular prion protein (PrP) remains to be fully elucidated; however, the protein is crucial for the infection and progression of prion diseases. Recent evidence indicates that PrP is a metalloprotein since the octapeptide repeat sequences in
Jerome A Roth et al.
Neurotoxicology, 35, 121-128 (2013-01-15)
Chronic exposure to Mn results in the development of a neurological disorder known as manganism characterized by neurological deficits resembling that seen in Parkinsonism. Although dopaminergic neurons within the nigrostriatal pathway appear intact, Mn-induced irregularities in DA transmission have been
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