推荐产品
蒸汽密度
3.59 (vs air)
质量水平
方案
≥99.5%
表单
liquid
纯化方式
redistillation
折射率
n20/D 1.346 (lit.)
沸点
68-69 °C (lit.)
mp
−34 °C (lit.)
密度
0.932 g/mL at 20 °C (lit.)
SMILES字符串
COB(OC)OC
InChI
1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
InChI key
WRECIMRULFAWHA-UHFFFAOYSA-N
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应用
Trimethyl borate can be used as:
- A reagent in the preparation of various trialkylamine−boranes from corresponding trialkylamines using lithium hydride/aluminum chloride catalyst.
- A source of boron in the synthesis of boron nitride (BN) nanotubes by thermal-heating chemical vapor deposition (TH-CVD) method.
- An electrolytic additive for electrochemical applications.
- A reagent along with lithium di-tert-butyl(2,2,6,6-tetramethylpiperidino)zincate (TMP-zincate) for the synthesis of 1-tert-butyl-3,4-dihydroisoquinoline from isoquinoline via ortho metalation reaction.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - STOT SE 1
靶器官
Eyes
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
12.2 °F - (own results)
闪点(°C)
-11 °C - (own results)
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Trimethyl borate-induced one-pot homologation reactions of isoquinoline with di-tert-butyl-TMP zincate
Seo HJ, et al.
Tetrahedron Letters, 52(29), 3747-3750 (2011)
Trimethyl borate as an electrolyte additive for high potential layered cathode with concurrent improvement of rate capability and cyclic stability
Wang Z, et al.
Electrochimica Acta, 184(1), 40-46 (2015)
Thermal-heating CVD synthesis of BN nanotubes from trimethyl borate and nitrogen gas.
Lin FH, et al.
Materials Chemistry and Physics, 107(1), 115-121 (2008)
One-Pot Synthesis of Ammonia-Borane and Trialkylamine-Boranes from Trimethyl Borate.
Veeraraghavan RP, et al.
Organic Letters, 14(24), 6119-6121 (2012)
Scott Gronert et al.
Journal of the American Society for Mass Spectrometry, 13(9), 1088-1098 (2002-09-27)
Using a quadrupole ion trap mass spectrometer, trimethyl borate was allowed to react with dihydrogen phosphate, deprotonated O-phosphoserine, and a set of hydrogen bonded complexes involving dihydrogen phosphate and neutral acids (phosphoric acid, acetic acid, serine, and O-phosphoserine). The reactions
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