推荐产品
蒸汽密度
3.59 (vs air)
质量水平
检测方案
≥99.5%
形式
liquid
纯化方式
redistillation
折射率
n20/D 1.346 (lit.)
bp
68-69 °C (lit.)
mp
−34 °C (lit.)
密度
0.932 g/mL at 20 °C (lit.)
SMILES字符串
COB(OC)OC
InChI
1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
InChI key
WRECIMRULFAWHA-UHFFFAOYSA-N
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应用
Trimethyl borate can be used as:
- A reagent in the preparation of various trialkylamine−boranes from corresponding trialkylamines using lithium hydride/aluminum chloride catalyst.
- A source of boron in the synthesis of boron nitride (BN) nanotubes by thermal-heating chemical vapor deposition (TH-CVD) method.
- An electrolytic additive for electrochemical applications.
- A reagent along with lithium di-tert-butyl(2,2,6,6-tetramethylpiperidino)zincate (TMP-zincate) for the synthesis of 1-tert-butyl-3,4-dihydroisoquinoline from isoquinoline via ortho metalation reaction.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - STOT SE 1
靶器官
Eyes
WGK
WGK 1
闪点(°F)
(own results)
闪点(°C)
(own results)
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Trimethyl borate-induced one-pot homologation reactions of isoquinoline with di-tert-butyl-TMP zincate
Seo HJ, et al.
Tetrahedron Letters, 52(29), 3747-3750 (2011)
Trimethyl borate as an electrolyte additive for high potential layered cathode with concurrent improvement of rate capability and cyclic stability
Wang Z, et al.
Electrochimica Acta, 184(1), 40-46 (2015)
Thermal-heating CVD synthesis of BN nanotubes from trimethyl borate and nitrogen gas.
Lin FH, et al.
Materials Chemistry and Physics, 107(1), 115-121 (2008)
R Meder et al.
Solid state nuclear magnetic resonance, 15(1), 69-72 (2000-07-21)
Boron-11 nuclear magnetic resonance imaging and spectroscopy have been used to characterise the nature and distribution of boron compounds after preservative treatment of radiata pine wood with trimethylborate (TMB). One day after treatment, 11B magnetic resonance imaging microscopy showed significant
Scott Gronert et al.
Journal of the American Society for Mass Spectrometry, 13(9), 1088-1098 (2002-09-27)
Using a quadrupole ion trap mass spectrometer, trimethyl borate was allowed to react with dihydrogen phosphate, deprotonated O-phosphoserine, and a set of hydrogen bonded complexes involving dihydrogen phosphate and neutral acids (phosphoric acid, acetic acid, serine, and O-phosphoserine). The reactions
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