质量水平
mp
181-184 °C (lit.)
SMILES字符串
CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
InChI
1S/C42H63O3P/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18/h19-27H,1-18H3
InChI key
JKIJEFPNVSHHEI-UHFFFAOYSA-N
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一般描述
三(2,4-二叔丁基苯基)亚磷酸酯是一种基于三芳基的亚磷酸酯,可用于催化和金属化。其可承受金属化反应且可提供高成本效益的合成方法,因而在联芳基偶联反应中具有重要应用价值。
应用
它可用作扩链剂和工艺稳定剂,有助于生产稳定的聚合材料,包括聚乳酸(PLA)、聚烯烃等。
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Orthopalladated triarylphosphite complexes as highly efficient catalysts in the Heck reaction.
Tetrahedron Letters, 39(52), 9793-9796 (1998)
Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions.
Chemical Communications (Cambridge, England), 19, 2095-2096 (1998)
Study of the high temperature reactions of a hindered aryl phosphite (Hostanox PAR 24) used as a processing stabiliser in polyolefins.
Polymer Degradation and Stability, 95(9), 1883-1893 (2010)
Structure effect of phosphite on the chain extension in PLA.
Polymer Degradation and Stability, 120(52), 283-289 (2015)
Journal of orthopaedic research : official publication of the Orthopaedic Research Society, 32(6), 757-761 (2014-02-19)
Antioxidant stabilization of radiation cross-linked ultrahigh molecular weight polyethylene (UHMWPE) has been introduced to improve the oxidative stability of total joint implant bearing surfaces. Blending of an antioxidant with UHMWPE resin powder followed by consolidation and radiation cross-linking has been
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