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方案
≥95%
表单
powder or crystals
mp
164-168 °C (lit.)
官能团
bromo
SMILES字符串
OB(O)c1cccc(Br)c1
InChI
1S/C6H6BBrO2/c8-6-3-1-2-5(4-6)7(9)10/h1-4,9-10H
InChI key
AFSSVCNPDKKSRR-UHFFFAOYSA-N
应用
Reactant involved in a variety of organic reactions including:
- Oxidative cross coupling
- Gold salt catalyzed homocoupling
- 1,4-Addition reactions with α,β-unsaturated ketones
- Enantioselective addition reactions
- Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids
- C-H Functionalization of quinones
其他说明
含不定量的酸酐
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
历史批次信息供参考:
分析证书(COA)
Organic letters, 6(13), 2205-2207 (2004-06-18)
[reaction: see text] A mixture of nitrate salt and chlorotrimethylsilane is found to be an efficient regioselective nitrating agent for the ipso-nitration of arylboronic acids to produce the corresponding nitroarenes in moderate to excellent yields. High selectivity, simplicity, and convenience
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