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关于此项目
经验公式(希尔记法):
C5H3BCl2F5N
化学文摘社编号:
分子量:
253.79
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
427-400-1
MDL number:
产品名称
2,6-二氯-1-氟吡啶四氟硼酸盐, 97%
InChI key
JVYBYXWHPIEUOT-UHFFFAOYSA-N
InChI
1S/C5H3Cl2FN.BF4/c6-4-2-1-3-5(7)9(4)8;2-1(3,4)5/h1-3H;/q+1;-1
SMILES string
F[B-](F)(F)F.F[n+]1c(Cl)cccc1Cl
assay
97%
mp
212-215 °C (lit.)
functional group
chloro
Quality Level
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Application
2,6-二氯-1-氟吡啶四氟硼酸盐可用于芴的区域选择性氟化反应。
General description
2,6-二氯-1-氟吡啶四氟硼酸盐在各种反应中广泛用作氟化试剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Fluorination of fluorene, dibenzofuran and their open analogues with caesium fluoroxysulfate and related fluorinating reagents.
Iskra J, et al.
Collection of Czechoslovak Chemical Communications, 73(12), 1671-1680 (2008)
Electrophilic NF Fluorinating Agents.
G. Sankar Lal et al.
Chemical reviews, 96(5), 1737-1756 (1996-08-01)
Oriol Planas et al.
Science (New York, N.Y.), 367(6475), 313-317 (2020-01-18)
Bismuth catalysis has traditionally relied on the Lewis acidic properties of the element in a fixed oxidation state. In this paper, we report a series of bismuth complexes that can undergo oxidative addition, reductive elimination, and transmetallation in a manner
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