436011
磷酸铁(III) 二水合物
Fe 29%, powder
别名:
二水磷酸铁
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关于此项目
线性分子式:
FePO4 · 2H2O
化学文摘社编号:
分子量:
186.85
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
磷酸铁(III) 二水合物, Fe 29 %
SMILES string
O.O.[Fe+3].[O-]P([O-])([O-])=O
InChI
1S/Fe.H3O4P.2H2O/c;1-5(2,3)4;;/h;(H3,1,2,3,4);2*1H2/q+3;;;/p-3
InChI key
BMTOKWDUYJKSCN-UHFFFAOYSA-K
form
powder
composition
Fe, 29%
reaction suitability
core: iron
reagent type: ligand
reaction type: Cross Couplings
functional group
amine
phosphine
Quality Level
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Application
磷酸铁(III)二水合物(FePO4 x 2H2O)可作为催化剂用于：
还用于合成碳包覆磷酸铁锂(LiFePO4)，作为锂离子电池的正极材料。它还是制备磷酸盐玻璃纤维的主要原料。
- 通过醛、β-酮酸酯和尿素/硫脲的一锅三组分Biginelli反应生成3,4-二氢嘧啶-2(1H)-酮和硫酮。
- 通过异丁酸甲酯(MIB)的氧化脱氢反应生成甲基丙烯酸甲酯(MMA)。
还用于合成碳包覆磷酸铁锂(LiFePO4)，作为锂离子电池的正极材料。它还是制备磷酸盐玻璃纤维的主要原料。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Wei Wang et al.
Chemical communications (Cambridge, England), 48(58), 7289-7291 (2012-06-16)
Novel iron phosphates microflowers which show SOD-like and peroxidase-like mimic activities were prepared, suggesting potential applications as a biocatalyst and a biosensor for H(2)O(2).
Structural and electrochemical study of a new crystalline hydrated iron (III) phosphate FePO4
Marx N, et al.
Chemistry of Materials, 22(5), 1854-1861 (2010)
Optimized LiFePO4--polyacene cathode material for lithium-ion batteries.
Xie H_M, et al.
Advanced Materials, 18(19), 2609-2613 (2006)
Synthesis and degradation of sodium iron phosphate glasses and their in vitro cell response
Parsons AJ, et al.
Journal of Biomedical Materials Research Part A, 71(2), 283-291 (2004)
Miran Gaberscek et al.
Physical chemistry chemical physics : PCCP, 9(15), 1815-1820 (2007-04-07)
We try to identify the rate-determining step of electrochemical kinetics of a LiFePO(4)-carbon composite electrode by varying the mass of electrode and, additionally, by varying the charge-discharge current in a wide range. It is shown that the reversible capacity is
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