所有图片(1)
别名:
(2-氨基乙基)二苯基膦, 1-氨基-2-（二苯基膦基）乙烷
经验公式（希尔记法）:
C14H16NP
CAS号:
分子量:
229.26
Beilstein:
644931
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
![(R)-1-[2-(Diphenylphosphino)phenyl]ethylamine 96%](/deepweb/assets/sigmaaldrich/product/structures/392/254/dca6c835-df80-4685-9f63-3424abbecd29/640/dca6c835-df80-4685-9f63-3424abbecd29.png)
质量水平
检测方案
≥95.0% (GC)
形式
liquid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
官能团
phosphine
SMILES字符串
NCCP(c1ccccc1)c2ccccc2
InChI
1S/C14H16NP/c15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-10H,11-12,15H2
InChI key
RXEPBCWNHKZECN-UHFFFAOYSA-N
一般描述
2-(二苯基膦基)乙胺是一种双齿结构的膦配体，磷原子提供两对孤对电子供金属离子配位。可用作反应剂，合成酰胺化合物选择性氢化反应的活性催化剂。它也被用作合成其他膦配体的前体。
应用
2-(二苯基膦基)乙胺可用作镍催化体系中的双齿配体，用于炔烃经还原[2+2]环加成合成环丁烯的反应。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Rhodium-P, O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions
Dalton Transactions, 39(8), 1929-1931 (2010)
A highly active catalyst for the hydrogenation of amides to alcohols and amines
Angewandte Chemie (International Edition in English), 50(44), 10377-10380 (2011)
Nickel-catalyzed reductive [2+ 2] cycloaddition of alkynes
Canellas S, et al.
Journal of the American Chemical Society, 140(50), 17349-17355 (2018)
Youngwon Kim et al.
Journal of inorganic biochemistry, 205, 111015-111015 (2020-02-08)
A pyrrolyl-iminophosphine (PNNH) which would act as a potential terdentate ligand has been prepared by Schiff base reaction. Complexes [M(PNN)X] (M = Ni; X = Cl (1), Pd; X = Cl (2), Br (3), I (4), M = Pt; X = Cl (5)) were prepared. The title complexes were characterized
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门