425508
2,6-二甲基苯基溴化镁 溶液
1.0 M in THF
别名:
2,6-Xylylmagnesium bromide, Bromo(2,6-dimethylphenyl)magnesium
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关于此项目
线性分子式:
(CH3)2C6H3MgBr
化学文摘社编号:
分子量:
209.37
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
2,6-二甲基苯基溴化镁 溶液, 1.0 M in THF
InChI
1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
SMILES string
Cc1cccc(C)c1[Mg]Br
InChI key
BIGUVDUZGAJWQK-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
bp
65-67 °C
density
0.998 g/mL at 25 °C
Quality Level
Application
2,6-Dimethylphenylmagnesium bromide can be used:
- As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin.
- As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
target_organs
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-2.2 °F - closed cup
flash_point_c
-19 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Pd (OAc) 2-catalyzed domino reactions of 1, 2-dihaloarenes and 2-haloaryl arenesulfonates with Grignard reagents: efficient synthesis of substituted fluorenes
Dong C and Hu Q
Tetrahedron, 64(11), 2537-2552 (2008)
Nearly Chromatography-Free Synthesis of the A3B-Porphyrin 5-(4-Hydroxymethylphenyl)-10, 15, 20-tri-p-tolylporphinatozinc (II).
Zaidi SHH, et al.
Organic Process Research & Development, 10(2), 304-314 (2006)
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