418633
焦磷酸四苄酯
98%
别名:
四苄基二磷酸酯, 焦磷酸四苄基酯
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关于此项目
线性分子式:
(C6H5CH2O)2P(O)OP(O)(OCH2C6H5)2
化学文摘社编号:
分子量:
538.47
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2068292
Assay:
98%
InChI
1S/C28H28O7P2/c29-36(31-21-25-13-5-1-6-14-25,32-22-26-15-7-2-8-16-26)35-37(30,33-23-27-17-9-3-10-18-27)34-24-28-19-11-4-12-20-28/h1-20H,21-24H2
SMILES string
O=P(OCc1ccccc1)(OCc2ccccc2)OP(=O)(OCc3ccccc3)OCc4ccccc4
InChI key
NSBNXCZCLRBQTA-UHFFFAOYSA-N
assay
98%
mp
63-66 °C (lit.)
functional group
phenyl, phosphate
storage temp.
−20°C
Quality Level
Application
焦磷酸四苄基可用于以下研究：
- Pb2+-选择性膜电极的制造。
- 制备合成核苷酸，3,6-二脱氧己糖的磷酸酯。
- 作为Und-PP-Bac（十一碳二烯基焦磷酸 = Und-PP；Bac =不寻常的糖杆菌胺）合成的磷酸化试剂。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
N S Utkina et al.
Bioorganicheskaia khimiia, 15(10), 1375-1383 (1989-10-01)
Interaction of lithium alcoholates of 2,4-di-O-benzoates of paratose and abequose with tetrabenzyl pyrophosphate gave alpha-phosphates of the 3,6-dideoxyhexoses, further converted into the corresponding cytidine-5'-diphosphate derivatives. These synthetic nucleotides were shown to participate in the biosynthesis of the O-specific polysaccharides for
Eranthie Weerapana et al.
Journal of the American Chemical Society, 127(40), 13766-13767 (2005-10-06)
The chemical synthesis and biological activity of undecaprenyl pyrophosphate bacillosamine (Und-PP-Bac), an obligatory intermediate in the asparagine-linked glycosylation pathway of Campylobacter jejuni, are reported. The key transformation involves the coupling of bacillosamine phosphate and undecaprenyl phosphate. The synthetic Und-PP-Bac can
The Journal of Organic Chemistry, 59, 2279-2279 (1994)
D Xu et al.
Talanta, 51(2), 365-371 (2008-10-31)
Tetrabenzyl pyrophosphate and diphenylphosphinic anhydride, with two phosphoryl groups (PO) as ligating sites, can be used as novel ionophores to make Pb(2+)-selective membrane electrodes. A good result was obtained with tetrabenzyl pyrophosphate, and the electrode based on this ionophore and
Solvolysis of Tetrabenzyl Pyrophosphate. Catalysis by Imidazole1
Blakeley R, et al.
Journal of the American Chemical Society, 88(1), 112-119 (1966)
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