417297
甲基氯化锌 溶液
2.0 M in THF
别名:
Chloromethylzinc
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关于此项目
线性分子式:
CH3ZnCl
化学文摘社编号:
分子量:
115.88
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
969141
产品名称
甲基氯化锌 溶液, 2.0 M in THF
InChI
1S/CH3.ClH.Zn/h1H3;1H;/q;;+1/p-1
SMILES string
C[Zn]Cl
InChI key
ASUSLKVOTPUROZ-UHFFFAOYSA-M
form
liquid
concentration
2.0 M in THF
bp
67 °C
density
1.033 g/mL at 25 °C
Quality Level
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Application
Methylzinc chloride can be used in:
- Ni-catalyzed one-pot Negishi coupling with amino-heteroaryl chlorides.
- Cross-coupling with aryl fluorides in the presence of a nickel catalyst.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
A convenient one-pot Negishi coupling of amino-heteroaryl chlorides and alkyl bromides
Walters IAS
Tetrahedron Letters, 47(3), 341-344 (2006)
Nickel-catalyzed cross-coupling of aryl fluorides and organozinc reagents
Zhu F and Wang Z
The Journal of Organic Chemistry, 79(10), 4285-4292 (2014)
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