质量水平
检测方案
97%
形式
liquid
折射率
n20/D 1.409 (lit.)
bp
73 °C/15 mmHg (lit.)
密度
0.912 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)OB1OC(C)(C)C(C)(C)O1
InChI
1S/C9H19BO3/c1-7(2)11-10-12-8(3,4)9(5,6)13-10/h7H,1-6H3
InChI key
MRWWWZLJWNIEEJ-UHFFFAOYSA-N
应用
2-异丙氧基-4,4,5,5-四甲基-1,3,2-二氧杂硼烷可用作芳烃硼化试剂,并用于制备芴基硼烷。
它也可以合成用于生成共轭共聚物的以下中间体:
它也可以合成用于生成共轭共聚物的以下中间体:
- 9,9-二辛基-2,7-双(4,4,5,5-四甲基-1,3,2-二氧杂硼烷-2-基)二苯并甲硅烷基。
- 3,9-双(4,4,5,5-四甲基-1,3,2-二氧杂硼硼烷-2-基)-5,11-二(1-癸基十一烷基)吲哚[3,2-b]咔唑。
- 2,7-双(4,4,5,5-四甲基-1,3,2-二氧杂硼烷-2-基)-9,9-二辛基芴。
- 2,7-双(4′,4′,5′,5′-四甲基-1′,3′,2′-二恶英-2′-基)-N-9′′-十七烷基咔唑。
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Indolo [3, 2-b] carbazole-based alternating donor?acceptor copolymers: synthesis, properties and photovoltaic application.
Journal of Materials Chemistry, 19(41), 7730-7737 (2009)
A low?bandgap poly (2, 7?carbazole) derivative for use in high?performance solar cells.
Advanced Materials, 19(17), 2295-2300 (2007)
Journal of the American Chemical Society, 126(22), 7041-7048 (2004-06-04)
We report the synthesis and photophysical study of a series of solution-processible phosphorescent iridium complexes. These comprise bis-cyclometalated iridium units [Ir(ppy)(2)(acac)] or [Ir(btp)(2)(acac)] where ppy is 2-phenylpyridinato, btp is 2-(2'-benzo[b]thienyl)pyridinato, and acac is acetylacetonate. The iridium units are covalently attached
Regioselective halogen-metal exchange reaction of 3-substituted 1, 2-dibromo arenes: The synthesis of 2-substituted 5-bromobenzoic acids
Synlett, 2006(12), 1948-1952 (2006)
Organic letters, 8(22), 5029-5032 (2006-10-20)
p-Tolyl-substituted ladder-type oligo(p-phenylene)s containing three, four, and five phenylene rings were readily synthesized. The uniform aryl substitution of these systems allowed us to determine the coplanarity of the pi-conjugated backbones crystallographically. The intramolecular annulations eliminate almost all of the conformational
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