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Merck
CN

412287

Sigma-Aldrich

均苯四甲酸酐

97%

别名:

1,2,4,5-苯四甲羧酸二酐, PMDA

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About This Item

经验公式(希尔记法):
C10H2O6
CAS号:
分子量:
218.12
Beilstein:
213583
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

97%

形式

powder

bp

397-400 °C (lit.)

mp

283-286 °C (lit.)

SMILES字符串

O=C1OC(=O)c2cc3C(=O)OC(=O)c3cc12

InChI

1S/C10H2O6/c11-7-3-1-4-6(10(14)16-8(4)12)2-5(3)9(13)15-7/h1-2H

InChI key

ANSXAPJVJOKRDJ-UHFFFAOYSA-N

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一般描述

均苯四甲酸二酐是二酐类单体,常用于制备聚酰亚胺聚合物,这类聚合物因其优异的热稳定性、高机械强度和固有的阻燃性而用于航空航天、电子和汽车工业领域。它还用于合成聚酯和聚醚等热塑性聚合物,以及增塑剂和环氧树脂。另外,PMDA还可作为环氧树脂的固化剂。环氧树脂广泛用于粘合剂、涂料、复合材料和电绝缘材料。

均苯四甲酸二酐(PMDA)是一种酸性酸酐,可作为修复剂和扩链剂用于聚对苯二甲酸乙二醇酯(PET)扩链反应。它主要用于生产热塑性塑料和其他涂料应用。

应用

PMDA可用作:
  • 单体,合成具有优良热机械性能和化学特性的芳香族聚酰亚胺。这些聚合物可应用于汽车和电子行业。
  • 封端剂,研发硅氧烷基杂化材料,在有机电子领域具有潜在应用。
  • 单体,制备和改性薄膜复合膜,用于水净化、气体分离和生物医学设备。
  • 单体,合成均苯四甲酸二酰亚胺共聚物,作为锂离子电池和钠离子电池的稳定性正极活性材料。

象形图

Health hazardCorrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

危险化学品

分析证书(COA)

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Ju-Young Choi et al.
Polymers, 11(3) (2019-04-10)
Polyimide films have conventionally been prepared by thermal imidization of poly(amic acid)s (PAAs). Here we report that the improvement of tensile strength while increasing (or maintaining) film flexibility of polyimide films was accomplished by simple microwave (MW) irradiation of the
Anastasia Anceschi et al.
Nanomaterials (Basel, Switzerland), 10(3) (2020-03-12)
Cyclodextrin (CD)-based polymers are known to efficiently form molecular inclusion complexes with various organic and inorganic guest compounds. In addition, they also have a great potential as metal complexes because deprotonated hydroxyls can strongly bind metal ions under alkaline conditions.
High-refractive-index thin films prepared from aminoalkoxysilane-capped pyromellitic dianhydride-titania hybrid materials
Chang C and Chen W
Journal of Polymer Science Part A: Polymer Chemistry, 39(19), 3419-3427 (2001)
Shadpour Mallakpour et al.
Amino acids, 43(4), 1605-1613 (2012-02-14)
In the present work, several novel optically active nanostructure poly(amide-imide)s (PAI)s were synthesized via step-growth polymerization reaction of chiral diacids based on pyromellitic dianhydride-derived dicarboxylic acids containing different natural amino acids such as L-alanine, S-valine, L-leucine, L-isoleucine, L-methionine, and L-phenylalanine
Anastasia Anceschi et al.
Molecules (Basel, Switzerland), 25(13) (2020-07-08)
Carbon-based materials with different morphologies have special properties suitable for application in adsorption, catalysis, energy storage, and so on. Carbon spheres and carbon monoliths are also nanostructured materials showing promising results. However, the preparation of these materials often require the

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